| Identification | Back Directory | [Name]
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ | [CAS]
376355-58-7 | [Synonyms]
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite
1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite
N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine
N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite | [Molecular Formula]
C28H26NO2P | [MDL Number]
MFCD08277033 | [MOL File]
376355-58-7.mol | [Molecular Weight]
439.492 |
| Chemical Properties | Back Directory | [Melting point ]
99-102 °C
| [Boiling point ]
578.4±53.0 °C(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [pka]
-0.31±0.20(Predicted) | [color ]
white | [Optical Rotation]
[α]/D -250±10°, c = 1 in toluene | [Sensitive ]
moisture sensitive | [InChI]
1S/C28H26NO2P/c1-21(23-13-5-3-6-14-23)29(22(2)24-15-7-4-8-16-24)32-30-27-19-11-9-17-25(27)26-18-10-12-20-28(26)31-32/h3-22H,1-2H3 | [InChIKey]
JISGHECLGYELKD-UHFFFAOYSA-N | [SMILES]
C[C@H](N([C@@H](C)c1ccccc1)P2Oc3ccccc3-c4ccccc4O2)c5ccccc5 |
| Questions And Answer | Back Directory | [Reaction]
- Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic substituted allylic halides to form branched chiral products from diverse Grignard reagents.
- Ligand for the copper catalyzed, highly enantioselective conjugate addition of diethylzinc to eneones and nitro olefins.
- Ligand for the nickel catalyzed, highly enantioselective hydrovinylation of alkenes.
- Ligand for the rhodium catalyzed, highly enantioselective hydroformylation of vinylarenes.
- Ligand for gold catalyzed asymmetric Intramolecular hydroamination of allenes
|
| Hazard Information | Back Directory | [Uses]
N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:
- In the iridium catalyzed allylic arylation.
- To prepare a copper complex (Cu2X2L3), which is used to detect the transmetalation intermediates in asymmetric addition reactions using ZnEt2.
| [reaction suitability]
reaction type: click chemistry |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
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https://www.sigmaaldrich.cn |
| Company Name: |
BePharm Ltd
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400-685-9117 |
| Website: |
www.bepharm.com |
| Company Name: |
Energy Chemical
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021-58432009 400-005-6266 |
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http://www.energy-chemical.com |
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