| Identification | Back Directory | [Name]
SALITHION | [CAS]
3811-49-2 | [Synonyms]
Salibal
Salibassa
SALITHION
Fenfosphorin
DIOXABENZOFOS
FENPHOSPHORIN
Salibal powder
dioxabenzophos
Salibal emulsion
Salithion powder
salithion (jmaf)
Salibassa powder
Salithion-sumitomo
SALITHION STANDARD
Salibassa emulsion
Salithion emulsion
Dioxabenzofos (Salithion)
dioxabenzophos (bsi, darft-iso)
saligenincyclicmethylphosphorothionate
Saligenin cyclic methyl phosphorothionate
1,3,2-Benzodioxaphosphorin,2-methoxy-,2-sulfide
2-METHOXY-1,3,2-BENZODIOXAPHOSPHOLINE-2-SULPHIDE
2-methoxy-4h-(1.3.2)benzodioxaphosphorin2-sulfide
2-Methoxy-4H-1,2,3-benzodioxaphosphorine-2-sulfide
2-Methoxy-4H-1,3,2-benzodioxaphosphinine 2-sulfide
2-methoxy-4H-1,3,2-benzodioxaphosphorin 2-sulphide
4H-1,3,2-Benzodioxaphosphorin, 2-methoxy-, 2-sulfide
2-methoxy-4-[H]-1,3,2-benzodioxaphosphorine-2-sulfide
4H-(1.3.2)Benzodioxaphosphorine, 2-methoxy-, 2-sulfide
o-methylcyclico,o-(methylene-o-phenylene)phosphorothioate
(RS)-2-Methoxy-4H-1,3,2δ5-benzodioxaphosphinine 2-sulfide
(RS)-2-Methoxy-4H-1,3,2δ5-benzodioxaphosphorine 2-sulfide
[2R,(+)]-2-Methoxy-4H-1,3,2-benzodioxaphosphorin-2-sulfide
[2S,(-)]-2-Methoxy-4H-1,3,2-benzodioxaphosphorin-2-sulfide
2-methoxy-4H-1,3,2-benzodioxaphosphorin 2-sulphide dioxabenzofos
phosphorothioicacid,cyclico,o-(methylene-o-phenylene)o-methylester
benzylalcohol,o-hydroxy-,cyclico,o-esterwitho-methylphosphorothioate
Phosphorothioic acid, cyclic O,O-(methylene-o-phenylene) O-methyl ester
phosphorothioicacid,o-methylester,cyclico,o-esterwitho-hydroxybenzylalcohol
8-methoxy-8-thioxo-7,9-dioxa-8$l^{5}-phosphabicyclo[4.4.0]deca-1,3,5-triene
8-methoxy-8-sulfanylidene-7,9-dioxa-8$l^{5}-phosphabicyclo[4.4.0]deca-1,3,5-triene
Phosphorothioic acid, O-methyl ester, cyclic O,O-ester with o-hydroxybenzyl alcohol | [EINECS(EC#)]
223-292-3 | [Molecular Formula]
C8H9O3PS | [MDL Number]
MFCD00210363 | [MOL File]
3811-49-2.mol | [Molecular Weight]
216.19 |
| Chemical Properties | Back Directory | [Melting point ]
55-56℃ (methanol ) | [Boiling point ]
approximate 274℃ | [density ]
1.37±0.1 g/cm3(Predicted) | [storage temp. ]
0-6°C | [form ]
neat | [Water Solubility ]
58mg/L(30 ºC) | [BRN ]
1875270 | [Henry's Law Constant]
4.7×10-1 mol/(m3Pa) at 25℃, MacBean (2012) | [InChI]
1S/C8H9O3PS/c1-9-12(13)10-6-7-4-2-3-5-8(7)11-12/h2-5H,6H2,1H3 | [InChIKey]
OUNSASXJZHBGAI-UHFFFAOYSA-N | [SMILES]
COP1(=S)OCc2ccccc2O1 | [EPA Substance Registry System]
Dioxabenzofos (3811-49-2) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N | [Risk Statements ]
24/25-39/25-51/53 | [Safety Statements ]
36/37-38-45-61 | [RIDADR ]
2783 | [WGK Germany ]
3 | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [HS Code ]
29349990 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Oral
Acute Tox. 4 Dermal
Aquatic Chronic 2 | [Toxicity]
chicken,LD50,oral,110mg/kg (110mg/kg),PERIPHERAL NERVE AND SENSATION: STRUCTURAL CHANGE IN NERVE OR SHEATHBEHAVIORAL: ATAXIA,Bochu Kagaku. Scientific Pest Control. Vol. 40, Pg. 49, 1975. |
| Hazard Information | Back Directory | [Chemical Properties]
The pure product is white needle-shaped crystals. Its mp is 55-56°C, and its vapor pressure is 0.63 Pa (25°C). It is easily soluble in acetone, benzene, ethanol, and ether, and soluble in cyclohexanone, toluene, xylene, and isobutyl ketone. Its solubility in water is 50 mg/L at 30°C. It is stable in weakly acidic or alkaline media. | [Uses]
Dioxabenzofos may be used as an analytical reference standard for the determination of the analyte in food, animal tissues, Oolong tea and vegetables/fruits by various chromatography techniques.', 'Refer to the productμs Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support. | [Definition]
ChEBI: Salithion is an organic thiophosphate. | [Production Methods]
Dioxabenzophos is commercially produced through a multi-step synthesis involving O-methyl (O-2-formylphenyl) phosphorochloridothioate as a key intermediate. The process typically includes condensation reactions with salicylic alcohol or related benzodioxaphosphorine derivatives, using reagents like sodium tetrahydroborate or potassium carbonate in solvents such as methanol, toluene, or dichloromethane. | [Mechanism of action]
Non-systemic with contact, stomach and respiratory action. Acetylcholinesterase (AchE) inhibitor. | [Pesticide Type]
Insecticide |
|
|