ChemicalBook--->CAS DataBase List--->38857-88-4

38857-88-4

38857-88-4 Structure

38857-88-4 Structure
IdentificationBack Directory
[Name]

BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE
[CAS]

38857-88-4
[Synonyms]

Bis(2,2,2-trichloroethyl) azodicarboxyle
BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE
Bis(2,2,2-trichloroethyl) azodicarboxylate
BEAZ Bis(2,2,2-trichloroethyl) azodicarboxylate
BIS(2,2,2-TRICHLOROETHYL) AZODI-CARBOXYL ATE, 97+%
AZODICARBOXYLIC ACID BIS(2,2,2-TRICHLOROETHYL) ESTER
1,2-Diazenedicarboxylic acid, 1,2-bis(2,2,2-trichloroethyl) ester
[Molecular Formula]

C6H4Cl6N2O4
[MDL Number]

MFCD00010607
[MOL File]

38857-88-4.mol
[Molecular Weight]

380.82
Chemical PropertiesBack Directory
[Melting point ]

109-111 °C(lit.)
[Boiling point ]

380.7±42.0 °C(Predicted)
[density ]

1.78±0.1 g/cm3(Predicted)
[storage temp. ]

2-8°C
[solubility ]

sol in a wide range of organic solvents.
[form ]

solid
[color ]

slightly yellow
[BRN ]

2141527
[CAS DataBase Reference]

38857-88-4
Hazard InformationBack Directory
[Chemical Properties]

Yellow powder or crystals
[Uses]

Bis(2,2,2-trichloroethyl) azodicarboxylate has been used:
  • in the asymmetric synthesis of substituted cycloalkyl[b]indoles
  • as amination reagent during the aza-ene reaction of different alkenes to yield the corresponding allyl amines
  • in para-directed amination of C2-alkyl substituted anisole
  • in the synthesis of acid- and base-sensitive azo compounds and in Diels-Alder cycloadditions
[General Description]

Thermal inverse-type hetero-Diels-Alder reaction of O-silyl-protected lactal and bis(2,2,2-trichloroethyl) azodicarboxylate has been reported.
[storage]

Bis(2,2,2-trichloroethyl) azodicarboxylate is same as with all azo compounds, caution should be exercised to avoid exposure of the material to heat. Store in a brown bottle.
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
Spectrum DetailBack Directory
[Spectrum Detail]

BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE(38857-88-4)1HNMR
BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE(38857-88-4)Raman
BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE(38857-88-4)IR
BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE(38857-88-4)FT-IR
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