| Identification | Back Directory | [Name]
3,6-DIBROMOTHIENO[3,2-B]THIOPHENE | [CAS]
392662-65-6 | [Synonyms]
BTH-3Sn
3,6-DIBROMOTHIENO[3,2-B]THIOPHENE
3,6-Dibromothieno[3,2-b]thiophene>
Thieno[3,2-b]thiophene, 3,6-dibromo-
3,6-DIBROMOTHIENO[3,2-B]THIOPHENE ISO 9001：2015 REACH | [Molecular Formula]
C6H2Br2S2 | [MDL Number]
MFCD10000958 | [MOL File]
392662-65-6.mol | [Molecular Weight]
298.03 |
| Chemical Properties | Back Directory | [Melting point ]
127 °C | [Boiling point ]
332.4±37.0 °C(Predicted) | [density ]
2.209±0.06 g/cm3(Predicted) | [storage temp. ]
Refrigerator | [form ]
powder to crystal | [color ]
White to Yellow to Orange | [InChI]
InChI=1S/C6H2Br2S2/c7-3-1-9-6-4(8)2-10-5(3)6/h1-2H | [InChIKey]
DFMPVYZMICAYCS-UHFFFAOYSA-N | [SMILES]
C12C(Br)=CSC=1C(Br)=CS2 |
| Hazard Information | Back Directory | [Synthesis]
The general procedure for the synthesis of 3,6-dibromothieno[3,2-b]thiophene from tetrabromothieno[3,2-B]thiophene was carried out as follows: tetrabromothieno[3,2-B]thiophene (9.12 g, 20 mmol), acetic acid (500 ml), and toluene (200 ml) were added to the reactor, followed by zinc powder (2.62 g, 40 mmol). The reaction mixture was filtered and the filtrate was concentrated to give the intermediate 3,6-dibromothieno[3,2-b]thiophene (5.36 g, 90% yield). After completion of the reaction, the synthesis of intermediate C-28-2 was carried out. | [References]
[1] Patent: CN107056798, 2017, A. Location in patent: Paragraph 0065; 0066; 0067
[2] Patent: WO2016/92065, 2016, A1. Location in patent: Page/Page column 21; 22
[3] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 22, p. 3465 - 3470
[4] Patent: CN103172646, 2016, B. Location in patent: Paragraph 0114-0116
[5] Chemical Communications, 2005, # 9, p. 1161 - 1163 |
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