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404573-66-6

404573-66-6 Structure

404573-66-6 Structure
IdentificationBack Directory
[Name]

Bis(cyclooctadiene)rhodium(Ⅰ)(tetrakis-[3,5-bis(trifluormethyl)phenyl]borate)
[CAS]

404573-66-6
[Synonyms]

Rh(1,5-cyclooctadiene)2][B((3,5-CF3)C6H3)4
Bis(1,5-cyclooctadiene)rhodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
Bis(cyclooctadiene)rhodium(Ⅰ)(tetrakis-[3,5-bis(trifluormethyl)phenyl]borate)
Bis(1,5-cyclooctadiene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrakis[3,5-bis(trifluoromethyl)phenyl]borate(1-) (1:1)
[Molecular Formula]

C30H46BF6Rh-
[MDL Number]

MFCD10567026
[MOL File]

404573-66-6.mol
[Molecular Weight]

634.393
Chemical PropertiesBack Directory
[Melting point ]

175 °C (decomp)(Solv: dichloromethane (75-09-2); hexane (110-54-3))
[storage temp. ]

-20°C
[form ]

solid
[InChIKey]

HQQAEXNVAYMZON-AUUWQFPRSA-N
[SMILES]

[Rh+].C1CC=CCCC=C1.C2CC=CCCC=C2.FC(F)(F)c3cc(cc(c3)C(F)(F)F)[B-](c4cc(cc(c4)C(F)(F)F)C(F)(F)F)(c5cc(cc(c5)C(F)(F)F)C(F)(F)F)c6cc(cc(c6)C(F)(F)F)C(F)(F)F
Safety DataBack Directory
[WGK Germany ]

WGK 3
[HS Code ]

28439000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Bis(1,5-cyclooctadiene)rhodium(I) tetrakis[bis(3,5-trifluoromethyl)phenyl]borate can be used as a catalyst for various transformations, including hydrogenation, intramolecular C-H alkenylation, cycloaddition of enynes, and reductive coupling reactions.
[reaction suitability]

core: rhodium
reagent type: catalyst
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