| Identification | Back Directory | [Name]
(R)-METHYL BOPHOZ(TM) | [CAS]
406681-09-2 | [Synonyms]
(s)-methyl bophoz
(S)-METHYL BOPHOZ(TM)
(R)-METHYL BOPHOZ(TM)
(S)-N-DIPHENYLPHOSPHINO-N-METHYL-((R)-2&
(S)-N-DIPHENYLPHOSPHINO-N-METHYL-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
(R)-N-DIPHENYLPHOSPHINO-N-METHYL-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
(S)-N-Methyl-N-diphenylphosphino-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine
(1S)-1-(Diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene
Ferrocene,1-(diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)MethylaMino]ethyl]-, (1S)-
(S)-1-[(R)-2-Diphenylphosphinoferrocenyl](N-Methyl)(N-diphenylphosphino)ethylaMine (S)-Me-Bophoz
(S)-N-Diphenylphosphino-N-methyl-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine Methyl BoPhoz
(S)-N-Diphenylphosphino-N-methyl-(R)-2-(diphenylphosphino)ferrocenylüethylamine, (S)-Methyl BoPhoz
(S)-N-DIPHENYLPHOSPHINO-N-METHYL-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE, (S)-METHYL BOPHOZ-
Methyl-BoPhoz, (1S)-1-(Diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene
(S)-N-Diphenylphosphino-N-methyl-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, (S)-Methyl BoPhoz^t
(S)-N-Diphenylphosphino-N-methyl-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, (S)-Methyl BoPhozTM | [Molecular Formula]
C37H35FeNP2 10* | [MDL Number]
MFCD05865220 | [MOL File]
406681-09-2.mol | [Molecular Weight]
611.47 |
| Chemical Properties | Back Directory | [Appearance]
Yellow to orange amorphous solid | [Melting point ]
80-82°C | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
solid | [color ]
yellow | [Optical Rotation]
Consistent with structure | [InChIKey]
ZIAZHUWEJYUGEO-FBHGDYMESA-N | [SMILES]
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6 |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow to orange amorphous solid | [Uses]
Methyl-BoPhoz can be used:
- As an efficient ligand for asymmetric hydrogenation reactions.
- To synthesize a single enantiomer of cyclopropylalanine via hydrogenation reaction using rhodium catalyst.
- To prepare chiral phenylalanine derivatives from α-amido cinnamic acids (or esters) using rhodium catalyst.
|
| Questions And Answer | Back Directory | [Reaction]
- Ligand used in the rhodium-catalyzed, asymmetric hydrogenation of β-amido-vinylphosphonates.
- Ligand used in the rhodium or iridium-catalyzed asymmetric hydrogenation of α,β-unsaturated esters.
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