| Identification | Back Directory | [Name]
N1-Methyl-4-nitro-o-phenyldiamin | [CAS]
41939-61-1 | [Synonyms]
41939-61-1
2-Methylamino-5-nitroaniline
N1-Methyl-4-Nitro-O-Phenyliamin
2-amino-4-nitro-N1-methylaniline
N1-Methyl-4-nitro-o-phenyldiamin
N1-Methyl-4-nitro-o-phenyldiaMine
N-Methyl-4-nitro-1,2-benzenediamine
1-Methyl-4-nitrobenzene-1,2-diaMine
3-Amino-4-(methylamino)nitrobenzene
N-Methyl-4-Nitro benzene-1,2-Diamine
N1-Methyl-4-nitrobenzene-1,2-diamine
N1-Methyl-4-nitro-o-phenylenediaMine
1,2-Diamino-N1-methyl-4-nitrobenzene
2-Amino-1-methylamino-4-nitrobenzene
1-(Methylamino)-4-nitrobenzen-2-amine
1-N-Methyl-4-nitrobenzene-1,2-diaMine
N’-Methyl-4-nitrophenylene-1,2-diamine
N~1~-methyl-4-nitro-1,2-benzenediamine
N1-Methyl-4-nitro-1,2-phenylenediamine
1,2-benzenediamine, N~1~-methyl-4-nitro-
N1-Methyl-4-nitro-1,2-phenylenediamine >
N~1~-Methyl-4-nitro-1,2-benzenediaMine, >95%
N1-Methyl-4-nitro-o-phenyldiamin ISO 9001：2015 REACH
N1-Methyl-4-nitro-1,2-phenylenediamine | [EINECS(EC#)]
808-144-3 | [Molecular Formula]
C7H9N3O2 | [MDL Number]
MFCD00156607 | [MOL File]
41939-61-1.mol | [Molecular Weight]
167.167 |
| Chemical Properties | Back Directory | [Melting point ]
174-176° | [Boiling point ]
366.8±32.0 °C(Predicted) | [density ]
1.358±0.06 g/cm3(Predicted) | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Ethyl Acetate (Slightly), Methanol (Slightly) | [form ]
Solid | [pka]
4.23±0.10(Predicted) | [color ]
Red Orange to Brown | [InChI]
InChI=1S/C7H9N3O2/c1-9-7-3-2-5(10(11)12)4-6(7)8/h2-4,9H,8H2,1H3 | [InChIKey]
MNIKERWISBANET-UHFFFAOYSA-N | [SMILES]
C1(NC)=CC=C([N+]([O-])=O)C=C1N | [CAS DataBase Reference]
41939-61-1 |
| Hazard Information | Back Directory | [Chemical Properties]
Red Powder | [Uses]
N’-Methyl-4-nitrophenylene-1,2-diamine (cas# 41939-61-1) is a compound useful in organic synthesis. | [Synthesis]
Step 2: Pd/C (10%) was added to a solution of N-methyl-2,4-dinitroaniline (12.14 g, 60.9 mmol) in acetonitrile (35 mL) and triethylamine (36.4 mL). The reaction mixture was cooled to -15 °C, followed by dropwise addition of formic acid (11.1 mL) to a solution of acetonitrile (35 mL). The reaction mixture was refluxed for 3 hours and then thermally filtered. The filtrate was concentrated under reduced pressure to afford N1-methyl-4-nitrobenzene-1,2-diamine (Product 2) as a red liquid in >95% yield. | [References]
[1] Organic and Biomolecular Chemistry, 2007, vol. 5, # 16, p. 2567 - 2571
[2] Patent: WO2010/85377, 2010, A2. Location in patent: Page/Page column 41
[3] Journal of the Indian Chemical Society, 1988, vol. 65, # 8, p. 567 - 570
[4] Patent: EP2769723, 2014, A1. Location in patent: Paragraph 0160-0161
[5] Patent: WO2014/128206, 2014, A1. Location in patent: Page/Page column 51 |
|
|