| Identification | Back Directory | [Name]
ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 | [CAS]
478980-03-9 | [Synonyms]
Umicore CX21
PALLADIUM(II)
(NHC)Pd(allyl)Cl
imidazol-2-ylidene]palladium(II)
UMicore CX21, 18% Pd, Product of UMicore
Allylchloro[1,3-bis(2,6-di-i-propylphenyl)
Allylchloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]palladium
ALLYLCHLORO[1,3-BIS-(DIISOPROPYLPHENYL)-IMIDAZOLE-2-YLIDENE]PALLADIUM(II)
Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) 98%
ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98
allyl(1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene)palladium(IV) chloride | [Molecular Formula]
C30H41ClN2Pd | [MDL Number]
MFCD08561131 | [MOL File]
478980-03-9.mol | [Molecular Weight]
571.53 |
| Chemical Properties | Back Directory | [Melting point ]
190°C (dec.) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2–8 °C | [form ]
Powder | [color ]
white | [InChI]
InChI=1S/Pd/q+2 | [InChIKey]
MUJIDPITZJWBSW-UHFFFAOYSA-N | [SMILES]
[Pd+2] |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow crystal | [Uses]
Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols. | [General Description]
Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) is an air-stable, well-defined palladium N-heterocyclic carbene complex, which can efficiently catalyze α-arylation of ketones. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for the cross-coupling of aryl chlorides with boronic acids.
- Catalyst for the diamination of conjugated dienes and trienes.
- Catalyst for the dehalogenation of aryl chlorides.
- Catalyst for anaerobic alcohol oxidation.
- Catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation.
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| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
T&W GROUP
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| Telephone: |
021-61551611 13296011611 |
| Website: |
www.trustwe.com/ |
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