| Identification | Back Directory | [Name]
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) | [CAS]
490023-37-5 | [Synonyms]
3,4-a′]dinaphthalen-4-yl)MethylaMine
(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL&
3,4-a']dinaphthalen-4-yl)methylamine 97%
3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99%
3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%
(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a
N-Benzyl-N-methyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
(11bS)-N-Methyl-N-(phenylmethyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)METHYLAMINE
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE | [Molecular Formula]
C28H22NO2P | [MDL Number]
MFCD04117686 | [MOL File]
490023-37-5.mol | [Molecular Weight]
435.45 |
| Chemical Properties | Back Directory | [Melting point ]
155-159 °C
| [alpha ]
+356° (c 0.32, CHCl3) | [Boiling point ]
635.4±48.0 °C(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [pka]
0.08±0.20(Predicted) | [color ]
white | [Sensitive ]
moisture sensitive | [InChI]
1S/C28H22NO2P/c1-29(19-20-9-3-2-4-10-20)32-30-25-17-15-21-11-5-7-13-23(21)27(25)28-24-14-8-6-12-22(24)16-18-26(28)31-32/h2-18H,19H2,1H3 | [InChIKey]
OHGGHRJGBXAKKY-UHFFFAOYSA-N | [SMILES]
CN(Cc1ccccc1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56 |
| Questions And Answer | Back Directory | [Reaction]
- The ligand has been used in Ir-catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines.
- The ligand has been used in the rhodium-catalyzed enantioselective hydrogenation of (E)-N-acylated dehydro-β-aminoacid esters.
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Energy Chemical
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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