| Identification | Back Directory | [Name]
3,3'-Dibromo-2,2'-bithiophene | [CAS]
51751-44-1 | [Synonyms]
Na &ge
3,3'
5,6'
2TH-2Bra
4,6,6'
-bithiophenyl
-Diamino-4'
-Oxy-venetoclax
5-Triiodo-&beta
-Bi-p-anisidine
-Diamino-5,5'
3-Bromo-2-(4'
-Dibromo-2,2'
-Dicyanobiphenyl
-Dinitro-5,5'
-Dibromo-5,5'
-Diformylbiphenyl
3-Chloro-4-(2'
-Dimethyl-1,1'
-diphenyl[4,4'
5-Trihydroxy-4'
-Dicarboxybenzidine
-Dibromodiphenyl-d8
-Dithiobis-L-valine
6-Nonabromobiphenyl
-Diindolyl disulfide
-Dichlorobisphenol A
-Trithiobis-D-valine
5-Heptachloro-1,1'
4-Pentachlorobiphenyl
-Dichlorobenzidine-d6
-Diindolyl Disulphide
-Thiodipropanoic Acid
5-Trichlorobisphenol A
-hydroxy-D/L-thyronine
-Diaminobenzidine 99+%
-Bisdemethylpinoresinol
-Hepta-O-pivaloyl-&alpha
-Dichlorobenzidine-13C12
-Pyridyl)-D-alanine 99+%
-bi-1H-pyrazole]-5,5'
-BIS(3, 5-CHOLESTADIENE)
5-Triiodo thyroacetic acid
-Bis(3-sulfopropyl)-5,5'
3,3'-DibroMo-2,2'-bithiop...
5-Triiodo-L-thyronine·
-bis(trimethylsilyl)-2,2'
5-Triiodo thyropropionic acid
3,3'-Dibromo-2,2'-bithiophene
3,3'-Dibromo-2,2'-dithiophene
-Diethyloxacarbocyanine Iodide
-Di-O-methylellagic acid 4'
-Dipentyloxacarbocyanine iodide
5-Triiodo-N-hydroxy-L-thyronine
-Trifluoromethylphenyl)propanol
-Dipropyloxacarbocyanine Iodide
-Methylenebis[5-bromo-saligenin
-Dibutylthiacarbocyanine Iodide
-Diethylthiacarbocyanine iodide
-Methylenebis[5-chlorosaligenin
5-Triiodo Thyroacetic Acid-13C6
-Dithiobis[6-nitrobenzoic Acid]
-Dioctylthiacarbocyanine Iodide
2,2'-Bithiophene, 3,3'-dibromo-
-Dipropylthiacarbocyanine iodide
3,3'-Dibromo-2,2'-bithiophene>
-Dithio(succinimidyl propionate)
-Methylenedisalicylic Acid-13C12
-Pyridyl)-DL-alanine 99+% (HPLC)
-Diethyloxadicarbocyanine Iodide
3,3'-Dibromo-2,2'-bithiophene 97%
-Methylene-bis(4-hydroxycoumarin)
5-Triiodo-L-thyronine sodium salt
-methoxystilbene 3-O-b-D-glucoside
5-Triiodothyronamine Hydrochloride
-Diethylthiatricarbocyanine iodide
-Dipropylthiadicarbocyanine iodide
-Chlorobenzyloxy)phenylboronic Acid
-Sulfonylbis[6-ethoxy-benzoic Acid]
-Dihexadecylcyclocarbocyanine iodide
-Bis(trimethylsilyl)biphenyl-4,4'
-diyl Bis(trifluoromethanesulfonate)
5-Triiodo Thyroacetic Acid n-Butyl Ester
3-bromo-2-(3-bromothiophen-2-yl)thiophene
-Diaminobenzidine tetrahydrochloride hydrate
-(Oxybis(methylene))bis(4-hydroxybenzaldehyde)
-Diindolylmethane (3,3-Methylenediindole, DIM)
-Dithiobis-1-propanesulfonic acid disodium salt
-Diaminobenzidine tetrahydrochloride hydrate &ge
-diphenyl-9-ethyloxacarbocyanine Betaine Sodium Salt
-Disulfanediylbis(4-amino-N-methylbenzenesulfonamide)
-[(4-Hydroxyphenyl)methylene]bis[4-hydroxybenzaldehyde
-[(4-Methoxyphenyl)methylene]bis[4-methoxybenzaldehyde
-Dithiobis[6-nitrobenzoic acid] bis(succinimide) ester
-Dithiobispropionic acid bis-sulfosuccinimidyl ester 90%
-(Propane-1,3-diyl)bis(7,8-dimethoxy-1H-benzo[d]azepin-2(3H)-one)
-[Thiobis(2,1-phenylene-2,1-diazenediyl)]bis[6-hydroxybenzoic Acid
-((Methylenebis(4,1-phenylene))bis(oxy))bis(1-(trityloxy)propan-2-ol)
-(Propane-1,3-diyl)bis(1-(prop-1-en-2-yl)-1H-benzo[d]imidazol-2(3H)-one)
-(Ethane-1,2-diylbis(oxy))bis(3,1-phenylene)diboronic Acid Pinacol Ester
-(Propane-1,3-diyl)bis(1-(prop-1-en-2-yl)-1H-benzo[d]imidazol-2(3H)-one)-d6
-((2-Hydroxypropane-1,3-diyl)bis(oxy))bis(4-chlorobenzoic acid) Diethyl Ester
-(Propane-1,3-diyl)bis(7,8-dimethoxy-4,5-dihydro-1H-benzo[d]azepin-2(3H)-one)
-(Isopropylazanediyl)bis(1-(4-((2-isopropoxyethoxy)methyl)phenoxy)propan-2-ol)
-(Butane-1,4-diyl)bis(1-vinyl-3-imidazolium) bis(trifluoromethanesulfonyl)imide
-(Propane-1,3-diyl)bis(7,8-dimethoxy-4,5-dihydro-1H-benzo[d]azepin-2(3H)-one)-d6
-(Naphthalene-1,3-diyl)bis(N-methyl-3-(thiophen-2-yl)propan-1-amine) Dihydrochloride
-(Propane-1,3-diyl)bis(2-oxo-2,3-dihydro-1H-benzo[d]imidazole-1-carboxylate) Di-tertbutyl Ester
-[[[3-[(1E)-2-(7-Chloro-2-quinolinyl)ethenyl]phenyl]methylene]bis(thio)]bis-propanoic Acid 1,1'
-Sulfonylbis(N-(4-cyano-3-(trifluoromethyl)phenyl)-2-hydroxy-2-methylpropanamide)|(Mixture of Diastereomers)
-methoxyflavone, DD1 (3-amino-2-(3-amino-4-methoxyphenyl)-4H-chromen-4-one, p76S6 Inhibitor, DD1, Proteasome Inhibitor, DD1) | [EINECS(EC#)]
663-413-0 | [Molecular Formula]
C8H4Br2S2 | [MDL Number]
MFCD00114806 | [MOL File]
51751-44-1.mol | [Molecular Weight]
324.05 |
| Chemical Properties | Back Directory | [Melting point ]
103°C | [Boiling point ]
318.6±37.0 °C(Predicted) | [density ]
1.951±0.06 g/cm3(Predicted) | [storage temp. ]
0-10°C | [solubility ]
soluble in Toluene | [form ]
powder | [color ]
White to Yellow to Orange | [InChI]
InChI=1S/C8H4Br2S2/c9-5-1-3-11-7(5)8-6(10)2-4-12-8/h1-4H | [InChIKey]
KBRZCEVRNLKHAZ-UHFFFAOYSA-N | [SMILES]
C1(C2SC=CC=2Br)SC=CC=1Br |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless solid | [Uses]
3,3'-Dibromo-2,2'-dithiophene is used in the preparation of benzothiadiazole copolymers which direct charge transport in thin-film transistors. Used in the synthesis of solar cells which are dithienop yrrole / anthracene based.
| [Uses]
suzuki reaction | [Application]
3,3'-Dibromo-2,2'-bithiophene can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and pharmaceutical and chemical production processes. | [Synthesis]
The freshly prepared LDA solution (prepared by the addition ofn-BuLi (2.5 M in hexanes, 100 mmol, 40 mL) and diisopropylamine(11.1 g, 110 mmol) in 50 mL of anhydrous THF (78 C to roomtemperature)) was added drop wise to a solution of 3-bromothiophene (16.30 g, 100 mmol) in anhydrous THF (100 mL)at 78 C under nitrogen atmosphere. The reaction mixture wasstirred for 1 h at 78 C and CuCl2 (14.11 g, 105 mmol)was added inone portion. The reaction mixture was allowed towarm up to roomtemperature and treated with aqueous HCl. The organic phaseseparated was collected and the aqueous phase was extracted withdiethyl ether several times. The combined organic phase was driedover anhydrous Na2SO4 and the solution was filtered, concentratedand the residue was purified by silica gel column chromatography(hexane eluent) to afford a the required compound as white solid(yield 85%).1H NMR (500 MHz, CDCl3, d ppm): 7.08 (d, J 5.0 Hz, 2H), 7.40(d, J 5.0 Hz, 2H). | [References]
[1] Organic Letters, 2010, vol. 12, # 18, p. 4054 - 4057
[2] Journal of Physical Organic Chemistry, 2017, vol. 30, # 9,
[3] Organic Electronics: physics, materials, applications, 2016, vol. 37, p. 312 - 325
[4] Physical Chemistry Chemical Physics, 2016, vol. 18, # 47, p. 32096 - 32106
[5] Journal of Organic Chemistry, 2012, vol. 77, # 23, p. 10931 - 10937 |
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J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
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0573-85285100 18627885956 |
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https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
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