| Identification | Back Directory | [Name]
DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) | [CAS]
52611-08-2 | [Synonyms]
Nsc148042
Bis(methyldiphenylphosphin
DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)
BIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE
Bis(methyldiphenylphosphine)palladium(II) Dichloride >
Dichlorobis[methylene-bis(diphenylphosphine)]dipalladium(II)
Bis(methyldiphenylphosphine)palladium(II) Dichloride (cis- and trans- mixture) | [Molecular Formula]
C26H26Cl2P2Pd | [MDL Number]
MFCD00216594 | [MOL File]
52611-08-2.mol | [Molecular Weight]
577.76 |
| Chemical Properties | Back Directory | [Melting point ]
>120*C (dec.) | [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
Chloroform (Slightly, Heated), DMSO (Slightly, Heated), Methanol (Slightly, Heat | [form ]
Solid | [color ]
Light Yellow to Yellow |
| Hazard Information | Back Directory | [Uses]
Catalyst for:
- Ullmann reactions (homocoupling reactions)
- Cross coupling reaction of tributyltin hydride with aryl iodides
- Double silylation, double carbonylation and cyclocarbonylation reactions
| [Application]
Dichlorobis(methyldiphenylphosphine)palladium(II) is a catalyst for the dicarbonylation of aryl halides with amines. | [Preparation]
Dichlorobis(methyldiphenylphosphine)palladium(II) is prepared by treating commercially available K2PdCl2 (in DMF) with methyldiphenylphosphine (in CH2Cl2), or from K2PdCl2 (in H2O) and methyldiphenylphosphine (in CH2Cl2) using Bu4NCl (in CH2Cl2) as a phase-transfer catalyst. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst |
|
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J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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https://www.jkchemical.com |
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Energy Chemical
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www.energy-chemical.com |
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T&W GROUP
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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