| Identification | Back Directory | [Name]
(-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE | [CAS]
528565-84-6 | [Synonyms]
(R,R)-PH-BPE-RH
(-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(R,R)-Ph-BPE-Rh | [Molecular Formula]
C42H48BF4P2Rh | [MDL Number]
MFCD07369037 | [MOL File]
528565-84-6.mol | [Molecular Weight]
804.49 |
| Chemical Properties | Back Directory | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
crystal | [color ]
orange | [Sensitive ]
air sensitive | [InChIKey]
HOYBXERAQSXVFT-FMUQXVHFSA-N | [SMILES]
[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2C[C@@H](P(CCP3[C@H](CC[C@@H]3c4ccccc4)c5ccccc5)[C@H]2c6ccccc6)c7ccccc7 |
| Questions And Answer | Back Directory | [Reactions]
1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.
2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.
3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.
4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.
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