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53042-33-4

53042-33-4 Structure

53042-33-4 Structure
IdentificationBack Directory
[Name]

LITHIUM DIMETHYLAMINOBOROHYDRIDE 1M SO&
[CAS]

53042-33-4
[Synonyms]

Tetraethylammoniun decahydrodecaborane
LITHIUM DIMETHYLAMINOBOROHYDRIDE 1M SO&
lithium dimethylaminoborohydride solution
Lithium dimethylaminoborohydride solution 1 M in THF
Lithium dimethylaminoborohydide 1.0 M in THF Cap: 100 ml
N-Methylmethanamine boron complex, Lithium (dimethylamino)trihydroborate, Lithium trihydro(N-methylmethanaminato)borate
[Molecular Formula]

C2H9BLiN
[MDL Number]

MFCD07784404
[MOL File]

53042-33-4.mol
[Molecular Weight]

64.8516
Chemical PropertiesBack Directory
[density ]

0.882 g/mL at 25 °C
[refractive index ]

n20/D 1.423
[Fp ]

0-1 °F
[storage temp. ]

2-8°C
[InChI]

1S/C2H9BN.Li/c1-4(2)3;/h1-3H3;/q-1;+1
[InChIKey]

CEDUMRZWZLVFKS-UHFFFAOYSA-N
[SMILES]

[Li+].[BH3-]N(C)C
Safety DataBack Directory
[Hazard Codes ]

F,C,Xn
[Risk Statements ]

11-14/15-19-34-40-36/37
[Safety Statements ]

16-26-29-33-36/37/39-43-45-36/37
[RIDADR ]

UN 3399 4.3/PG 1
[WGK Germany ]

1
[Storage Class]

4.3 - Hazardous materials which set free flammable gases upon contact with water
[Hazard Classifications]

Acute Tox. 4 Oral
Carc. 2
Eye Irrit. 2
Flam. Liq. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
Hazard InformationBack Directory
[Uses]

Lithium Aminoborohydride (LAB) Reagents

Reactant for:
  • B-H oxidative addition reactions
  • Reduction and amination reactions
  • Reduction of N-alkyl lactams
  • Synthesis of tertiary amine-boranes
[Uses]

Capable of reducing a variety of fuctional groups.5,6,7,8
[General Description]

Lithium dimethylaminoborohydride is a reagent exhibiting dual properties like a metal hydride and nitrogen nucleophile. It is generally considered as an alternative to lithium aluminum hydride (LAH) for the reduction of carbonyl compounds, amides, and lactams.
[reaction suitability]

reagent type: reductant
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