| Identification | Back Directory | [Name]
(S,S)-F-BINAPHANE | [CAS]
544461-38-3 | [Synonyms]
(S,S)-F-BINAPHANE
1,1'-Bis[(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino]ferrocene
1,1'-Bis{(S)-4,5-dihydro-3H-binaphtho[1,2-c:2',1'-e]phosphino}ferrocene, Min. 98% (S,S)-f-Binaphane
1,1μ-Bis[(S)-4,5-dihydro-3H-binaphtho[2,1-c:1μ,2μ-e]phosphepino]ferrocene, 1,1μ-Bis[(11bs)-3,5-dihydro-4H-dinaphtho[2,1-c:1μ,2μ-e]phosphenpin-4yl]ferrocene | [Molecular Formula]
2C27H20P.Fe | [MDL Number]
MFCD09842757 | [MOL File]
544461-38-3.mol | [Molecular Weight]
806.703 |
| Chemical Properties | Back Directory | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
Powder | [color ]
yellow-brown | [Sensitive ]
air sensitive, light sensitive |
| Questions And Answer | Back Directory | [Reaction]
- Ligand for enantioselective Pd-catalyzed hydrogenation of enesulfonamides [5] and cyclic Nsulfonylimines.
- Enantioselective, asymmetric organocatalyst for cycloaddition of allenoates to C60 fullerene (conversion >90%, ee up to 90%)
- Ligand for Iridium-mediated direct asymmetric reductive amination of acetophenone with phenylhydrazide (conversion >99%; yield >94%; ee >94%)
- Ligand used for the palladium-catalyzed, asymmetric, decarboxylative generation and asymmetric allylation of α-imino anions.
- Ligand used in iridium-catalyzed, asymmetric hydrogenation of 6-substituted 3-hydroxypyridinium salts to trans 6-substituted piperidin-3-ols with high enantioselectivities(up to 95% ee).
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