| Identification | Back Directory | [Name]
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE | [CAS]
54575-49-4 | [Synonyms]
K-selectride
K-SELECTRIDE(R)
insuresealtmbottle
k-selectride solution
K-Selectride(R) solution
(ca. 1.0Mol/L in Tetrahydrofuran)
Potassium tri(s-butyl)borohydride
Potassium tri-sec-butylborohyride
potassium tri-sec-butylhydroborate
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
Potassium tris(s-butyl)hydroborate(1-)
Potassium tri-sec-butylhydroborate(1-)
PotassiuM Tri-sec-butylborohydride
Potassium Tri-sec-
Butylborohydride in THF
Potassiumtri-sec-butylborohydride1.0MinTHF
potassium tri-sec-butylborohydride solution
potassiumtri-sec-butylborohydride,calselect?k,
K-SELECTRIDE, 1.0M SOLUTION IN TETRAHYDR OFURAN
potassium,(beta-4)-borate(1-hydrotris(1-methylpropyl)-
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE SOLUT ION, 1 M IN THF
Borate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)-
Potassiumtri-sec-butylborohydride,1.0MinTHF,inSure/Sealbottle
potassiumtri-sec-butylborohydride,calselect?k,intetrahydrofuran
Potassium tri-sec-butylborohydride, in tetrahydrofuran, 1M solution
Potassium tri-sec-butylborohydride, 1 M solution in tetrahydrofuran
Potassium Tri-sec-butylborohydride (ca. 1.0mol/L in Tetrahydrofuran)
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE, 1.0M IN THF, IN SURE/SEAL TM BOTTLE
K-Selectride(R) solution 1.0 M potassiuM tri-sec-butylborohydride in THF
Potassium tri-sec-butylborohydride1M solution in tetrahydrofuranAcroSeal§3
Potassium tri-sec-butylborohydride, 1M solution in tetrahydrofuran, AcroSeal | [EINECS(EC#)]
259-241-7 | [Molecular Formula]
C12H28BK | [MDL Number]
MFCD00009324 | [MOL File]
54575-49-4.mol | [Molecular Weight]
222.26 |
| Chemical Properties | Back Directory | [Appearance]
clear slightly yellow solution | [density ]
0.913 g/mL at 25 °C
| [Fp ]
1 °F
| [storage temp. ]
Flammables + water-Freezer (-20°C)e area | [form ]
Solution | [color ]
Clear slightly yellow | [Sensitive ]
moisture sensitive | [InChI]
InChI=1S/C12H25B.K/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h13H,7-9H2,1-6H3;/q-1;+1 | [InChIKey]
WRYQJJOHBLICCR-UHFFFAOYSA-N | [SMILES]
[B+3]([H-])([C-](C)CC)([C-](C)CC)[C-](C)CC.[K+] | [EPA Substance Registry System]
Borate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)- (54575-49-4) |
| Hazard Information | Back Directory | [Chemical Properties]
clear slightly yellow solution | [Uses]
Reducing reagent. Reactant for: Preparation of a PCP-pincer palladium hydride-K-Selectride complex. Formation of P-H, P-C, and C-H bonds by hydride attack. Stereoselective conjugate hydride reduction reactions. | [Uses]
Mild reducing agents in organic synthesis. | [Description]
Potassium tri-sec-butylborohydride [54575- 49-4] solution in tetrahydrofuran (THF) is sold as K-Selectride (Aldrich). These compounds may be used for highly stereoselective reductions, e.g., of ketones . Chemical rearrangements induced by potassium hydride are important in organic chemistry. Furthermore, in combination with other reagents potassium hydride acts as a catalyst in the polymerization of alkenes and dienes. | [reaction suitability]
reagent type: reductant |
| Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
11-15-34-37-19-14/15-40 | [Safety Statements ]
16-26-36/37/39-43-45 | [RIDADR ]
UN 3399 4.3/PG 1
| [WGK Germany ]
3
| [F ]
10 | [TSCA ]
TSCA listed | [HS Code ]
29310099 | [Storage Class]
4.3 - Hazardous materials which set free flammable gases upon contact with water | [Hazard Classifications]
Carc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Water-react 1 |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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https://www.jkchemical.com |
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Energy Chemical
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Maya High Purity Chemicals
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Infinity SCI
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3A Chemicals
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400-668-9898 |
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