ChemicalBook--->CAS DataBase List--->568-93-4

568-93-4

568-93-4 Structure

568-93-4 Structure
IdentificationBack Directory
[Name]

Acid Mordant Orange 14
[CAS]

568-93-4
[Synonyms]

C.I.58015
3-Nitroalizarine
Mordant orange 14
Alizarine Orange A
C.I.Mordant Orange 14
Acid mordant Orange 14
C.I.Mordant Orange 14:C.I.58015
1,2-Dihydroxy-3-nitroanthraquinone
1,2-dihydroxy-3-nitroanthracene-9,10-dione
9,10-Anthracenedione, 1,2-dihydroxy-3-nitro-
[EINECS(EC#)]

209-310-2
[Molecular Formula]

C14H7NO6
[MDL Number]

MFCD00019145
[MOL File]

568-93-4.mol
[Molecular Weight]

285.21
Chemical PropertiesBack Directory
[Melting point ]

244°C (rough estimate)
[Boiling point ]

427.65°C (rough estimate)
[density ]

1.3989 (rough estimate)
[refractive index ]

1.4700 (estimate)
[storage temp. ]

-20°C Freezer, Under inert atmosphere
[solubility ]

Dichloromethane (Slightly), DMSO (Slightly)
[form ]

Solid
[pka]

3.95±0.20(Predicted)
[color ]

Dark Yellow to Very Dark Yellow
[NIST Chemistry Reference]

3-Nitroalizarine(568-93-4)
Hazard InformationBack Directory
[Uses]

1,2-Dihydroxy-3-nitroanthraquinone (cas# 568-93-4) is useful for the development of allosteric PGAM1 inhibitors that are effective at suppressing the proliferation of pancreatic ductal adenocarcinoma cells.
[Uses]

Dyes cloth mordanted with Al orange, with Fe red to violet. As indicator in satd alcohol solution. pH 2.0-4.0, color change from golden orange to flat yellow (in water). pH 5.0-6.5 from yellow to purplish red.
[Preparation]

(a) in the presence of boric acid 1,2-Dihydroxyanthracene-9,10-dionein sulfuric acid in the nitration; (b) 1,2-Dihydroxyanthracene-9,10-dionein glacial acetic acid, toluene, petroleum ether or the nitration of nitrobenzene.
[Properties and Applications]

red light brown (chromium), red orange (aluminum). Insoluble in water. In concentrated sulfuric acid to orange, dilution after yellow.
Standard Ironing Fastness Light Fastness Fulling Persperation Fastness Soaping Water
Alkali Acid
ISO 3-4 6 3-4 4 4 4 3-4
[Purification Methods]

Crystallise the dye from AcOH (m 244-245o). It has max at 494nm (H2SO4) and forms Cu salts. [Beilstein 8 H 447, 8 II 491, 8 III 3774, 8 IV 2359.]
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