| Identification | Back Directory | [Name]
BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97 | [CAS]
57357-20-7 | [Synonyms]
(di-tert-butylcarbonyloxyiodo)benzol
[BIS(T-BUTYLCARBONYLOXY)IODO] BENZENE
BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97
Bis(tert-butylcarbonyloxy)iodobenzene 97%
Iodine, bis(2,2-dimethylpropanoato-κO)phenyl-
phenyl-l3-iodanediyl bis(2,2-dimethylpropanoate)
2-(2,2-dimethylpropanoyloxy)-3-iodophenyl]2,2-dimethylpropanoate
(Di-tert-butylcarbonyloxyiodo)benzol, 2,2-Dimethylpropanoic acid, phenyliodine complex, Bis(2,2-dimethylpropanoato-O)phenyliodide, Di-(Pivaloyloxy)iodobenzene | [Molecular Formula]
C16H23IO4 | [MDL Number]
MFCD08276835 | [MOL File]
57357-20-7.mol | [Molecular Weight]
406.254 |
| Chemical Properties | Back Directory | [Melting point ]
104-109 °C
| [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
powder to crystal | [color ]
White to Light yellow | [InChI]
InChI=1S/C16H23IO4/c1-15(2,3)13(18)20-17(12-10-8-7-9-11-12)21-14(19)16(4,5)6/h7-11H,1-6H3 | [InChIKey]
DZKPLZUSZXYHFB-UHFFFAOYSA-N | [SMILES]
C1C=CC=C(I(OC(=O)C(C)(C)C)OC(=O)C(C)(C)C)C=1 |
| Hazard Information | Back Directory | [Uses]
Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination
Reagent for:
- Preparation of α,β-unsaturated-γ-lactams via Rh-catalyzed C-H amination of allene carbamates, then Ru-catalyzed cyclocarbonylation
- Palladium-catalyzed diamination
- Preparation of functionalized bicyclic heterocyclic compounds by rhodium-catalyzed allene amidation and cyclization
- Preparation of piperidine and pyrrolidine derivatives via copper-catalyzed intramolecular aminoacetoxylation of aminoolefins
- C-H acyloxylation of arenes
- Hypervalent iodine oxidant
| [reaction suitability]
reagent type: catalyst
reaction type: C-H Activation
reagent type: oxidant |
|
| Company Name: |
TCI Europe
|
| Tel: |
320-37350700 |
| Website: |
https://www.tcichemicals.com/de/de/index.html |
| Company Name: |
TCI AMERICA
|
| Tel: |
800-4238616 |
| Website: |
https://www.tcichemicals.com/en/us/index.html |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|