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577971-19-8

577971-19-8 Structure

577971-19-8 Structure
IdentificationBack Directory
[Name]

2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA&
[CAS]

577971-19-8
[Synonyms]

2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA&
2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) acetate 97%
Acetato(2'-di-t-butylphosphino-1,1'-biphenyl-2-yl)palladiuM(II),97%
Acetato(2'-di-t-butylphosphino-1,1'- biphenyl-2-yl)palladium(II), min. 98% 
palladium, (acetato-Κo) [2'-[bis (1,1 dimethylethyl) phosphino-Κp] [1,1'-biphenyl]-2-yl Κc]
Palladium, (acetato-Κ:O) [2μ-[bis (1,1 dimethylethyl) phosphino-Κ:P] [1,1μ-biphenyl]-2-yl Κ:C]
[Molecular Formula]

C22H29O2PPd
[MDL Number]

MFCD04117716
[MOL File]

577971-19-8.mol
[Molecular Weight]

462.863
Chemical PropertiesBack Directory
[Melting point ]

130-140 °C (dec.)(lit.)
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[form ]

Powder
[color ]

off-white
[InChI]

InChI=1S/C20H26P.C2H4O2.Pd/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2(3)4;/h7-12,14-15H,1-6H3;1H3,(H,3,4);/q;;+1/p-1
[InChIKey]

IEYDYAASBZOBOC-UHFFFAOYSA-M
[SMILES]

C1(=CC=CC=C1C1C=CC=CC=1[Pd]OC(C)=O)P(C(C)(C)C)C(C)(C)C
Safety DataBack Directory
[WGK Germany ]

3
[Storage Class]

13 - Non Combustible Solids
Questions And AnswerBack Directory
[Uses]

Air and thermally stable, one-component precatalyst for the amination of aryl halides.
uses of 2-(2'-DI-TERT-BUTYLPHOSPHINE)BIPHENYLPA&
Hazard InformationBack Directory
[General Description]

2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) acetate is a novel, air- and moisture-and thermally stable catalyst.
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
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