ChemicalBook--->CAS DataBase List--->5826-73-3

5826-73-3

5826-73-3 Structure

5826-73-3 Structure
IdentificationBack Directory
[Name]

DIMETHYL 5-NORBORNENE-2,3-DICARBOXYLATE
[CAS]

5826-73-3
[Synonyms]

NISY
Dimalone
Dimelone
Compound-3916
Compound 3,916
Dimethylkarbat
DIMETHYL CARBATE
5-Norbornene-2-yl
TIMTEC-BB SBB008177
DIMETHYL 5-NORBORNENE-2,3-DICARBOXYLATE
dimethyl8,9,10-trinorborn-5-ene-2,3-dicarboxylate
Dimethyl 5-bicyclo(2.2.1)hepten-2,3-dicarboxylate
dimethylester,cis-5-norbornene-3-dicarboxylicacid
cis-5-norbornene-2,3-dicarboxylicaciddimethylester
5-Norbornene-2,3-dicarboxylic acid, dimethyl ester
DIMETHYL BICYCLO[2.2.1]-5-HEPTENE-2,3-DICARBOXYLATE
Dimethyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate
Norborna-5-ene-2,3-dicarboxylic acid dimethyl ester
cis-5-Norbornene-2,3-dicarboxylic acid dimethyl ester
dimethylcis-bicyclo(2,2,1)-5-heptene-2,3-dicarboxylate
Dimethyl cis-bicyclo(2.2.1)-5-heptene-2,3-dicarboxylate
5-Norbornene-2,3-dicarboxylic acid, dimethyl ester, cis-
cis-bicyclo(2,2,1-heptene-2,3-dicarboxylicacid)methylester
icyclo[2.2.1]hept-2-ene-5,6-dicarboxylic acid, dimethyl ester
icyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid, dimethyl ester
cis-Bicyclo(2,2,1)-heptene-2,3-dicarboxylic acid, methyl ester
dimethylesterkyselinybicyklo(2,2,1)hept-5-en-2,3-dikarboxylove
Bicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester
Bicyclo[2.2.1]hepta-2-ene-5,6-dicarboxylic acid dimethyl ester
cis-bicyclo(2.2.1)hept-5-ene-2,3-dicarboxylicacid,dimethylester
Dimethylester kyseliny bicyklo(2,2,1)hept-5-en-2,3-dikarboxylove
cis-Bicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester
cis-Bicyclo(2,2,1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester
Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid, 2,3-dimethyl ester
cis-3,6-endomethylene-delta(sup4)-tetrahydrophthalicaciddimethylester
(endo,endo)-bicyclo(2.2.1)hept-5-ene-2,3-dicarboxylicaciddimethylester
cis-3,6-Endomethylene-delta(sup4)-tetrahydrophthalic acid dimethylester
(endo,endo)-Bicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid dimethyl ester
Dimethyl bicyclo[2.2.1]-5-heptene-2,3-dicarboxylate~Dimethyl carbate~5-Norbornene-2,3-dicarboxylic acid dimethyl ester
[Molecular Formula]

C11H14O4
[MDL Number]

MFCD00154455
[MOL File]

5826-73-3.mol
[Molecular Weight]

210.23
Chemical PropertiesBack Directory
[Melting point ]

38°C
[Boiling point ]

150-152°C 20mm
[density ]

1.0410 (rough estimate)
[refractive index ]

1.4389 (estimate)
[Fp ]

150-152°C/20mm
[storage temp. ]

Storage temp. 2-8°C
[Appearance]

Colorless to light yellow Liquid
[Water Solubility ]

13.03g/L(35 ºC)
[Merck ]

14,3240
[BRN ]

1248588
[EPA Substance Registry System]

Dimethyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate (5826-73-3)
Safety DataBack Directory
[Risk Statements ]

22-36/38
[Safety Statements ]

26-36/37/39
[RTECS ]

RB8925000
Hazard InformationBack Directory
[Chemical Properties]

Mosquito repellent pure product is colorless crystal or colorless oily liquid, melting point 38 ℃. Industrial product melting point is 32 ℃; boiling point 110 ℃ (15mmHg), 129 ~ 130 ℃ ( 9mmHg); relative density 1.1642 (25 ℃), 1.1637 (35 ℃), solubility in water (35 ℃) 1.32g/100mL, soluble in methanol, ethanol, benzene, xylene and other organic solvents, soluble in esters.
[Uses]

Dimethyl carbate (DMC) is a green and multi-functional solvent that can be used as a solvent in lithium-ion batteries. Methylating agents in organic synthesis; It is also used in the production of polycarbonate, lubricants, polyurethane, cleaning and degreasing solvents, building materials such as paints and adhesives, fuel additives, and biodiesel production, etc. In addition, it can also be used as an insect repellant.
[Definition]

ChEBI: Dimethylcarbate is a dicarboxylic acid.
[Synthesis]

5-Norbornene-exo-2,3-dicarboxylic anhydride (exo-NDA), widely used in the synthesis of medicine and pesticide, was primarily obtained through the subsequent thermal isomerization of 5-norbornene-endo-2,3-dicarboxylic anhydride (endo-NDA) synthesized from cyclopentadiene (CPD) and maleic anhydride (MAH).[1]
[References]

[1] One-pot synthesis of 5-norbornene-2,3-dicarboxylic anhydride with high exo/endo ratio in a microreactor under high temperature and appropriate pressure. DOI:10.1016/j.cej.2024.155561
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