| Identification | Back Directory | [Name]
1-ADAMANTYLOXYCARBONYL FLUORIDE | [CAS]
62087-82-5 | [Synonyms]
ADOC-F
1-ADOC-F
ADAMANTYL FLUOROFORMATE
1-ADAMANTYL FLUOROFORMATE
1-ADAMANTYLOXYCARBONYL FLUORIDE
1-ADAMANTYL FLUOROFORMATE, 90+%
Adamantan-1-yl carbonofluoridate
1-Adamantyl carbonofluoridic acid
Fluoroformic acid adamantan-1-yl ester
Fluoridocarbonic acid 1-adamantyl ester
(tricyclo(3,3,1,1,3,7)decan-1-yl) fluoroformate
Fluoroformic acid tricyclo[3.3.1.13,7]decan-1-yl ester
Carbonofluoridic acid,tricyclo[3.3.1.13,7]dec-1-yl ester | [EINECS(EC#)]
263-400-6 | [Molecular Formula]
C11H15FO2 | [MDL Number]
MFCD00074772 | [MOL File]
62087-82-5.mol | [Molecular Weight]
198.23 |
| Chemical Properties | Back Directory | [Melting point ]
30-32 °C (lit.) | [Fp ]
192 °F
| [storage temp. ]
2-8°C | [form ]
solid | [BRN ]
3590131 | [Major Application]
peptide synthesis | [InChI]
1S/C11H15FO2/c12-10(13)14-11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2/t7-,8+,9-,11- | [InChIKey]
PNLZKVOKOVFGMZ-KJZNFTALSA-N | [SMILES]
FC(=O)OC12C[C@H]3C[C@H](C[C@H](C3)C1)C2 |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
34 | [Safety Statements ]
26-36/37/39-45 | [RIDADR ]
UN 2921 8/PG 1
| [WGK Germany ]
3
| [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Hazard Information | Back Directory | [Uses]
peptide synthesis | [Purification Methods]
Dissolve it in n-hexane (ca 10g in 150 mL) and keep at 0o for 24hours. Any 1-adamantanol present will separate. Filter and evaporate to dryness. The crystalline residue has m 31-32o and is recrystallised from n-hexane (90g/500mL), (IR (KBr): max 1242, 1824 and 2340 cm-1). There should be no OH str band above 2500 cm-1. [Moroder et al. Hoppe-Seyler’s Z Physiol Chem 357 1647 1976, cf Haas et al. J Am Chem Soc 88 1988 1966.] |
|
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