ChemicalBook--->CAS DataBase List--->63936-85-6

63936-85-6

63936-85-6 Structure

63936-85-6 Structure
IdentificationBack Directory
[Name]

Chloro(1,5-cyclooctadiene)methylpalladium(II) 97%
[CAS]

63936-85-6
[Synonyms]

ChloroMethyl(1
Cyclooctadienylmethylpalladium chloride
Chloro(1,5-cyclooctadiene)methylpalladium(II) 97%
Chloro(1,5-cyclooctadiene)MethylpalladiuM(II),97%
CHLOROMETHYL(1,5-CYCLOOCTADIENE)PALLADIUM(II),99%
ChloroMethyl(1,5-cyclooctadiene)palladiuM(II), 99%
Carbanide,chloropalladium(1+),(1Z,5Z)-cycloocta-1,5-diene
[Molecular Formula]

C9H14ClPd+
[MDL Number]

MFCD16621448
[MOL File]

63936-85-6.mol
[Molecular Weight]

264
Chemical PropertiesBack Directory
[Melting point ]

124-129 °C
[Fp ]

97℃
[storage temp. ]

-20°C, stored under nitrogen
[form ]

Powder
[color ]

light grey
[Sensitive ]

air sensitive, store cold
[InChI]

1S/C8H12.CH3.ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;1H3;1H;/q;;;+1/p-1/b2-1-,8-7-;;;
[InChIKey]

PPNGAOYQLFBHIK-PHFPKPIQSA-M
[SMILES]

C[Pd]Cl.C1CC=CCCC=C1
Safety DataBack Directory
[Symbol(GHS) ]

Skull and Crossbones (GHS06)Health Hazard (GHS08)Environment (GHS09)
GHS06,GHS08,GHS09
[Signal word ]

Danger
[Hazard statements ]

H301-H310-H315-H319-H332-H335-H372-H411
[Precautionary statements ]

P262-P273-P280-P301+P310+P330-P302+P352+P310-P304+P340+P312
[Hazard Codes ]

T+,N
[Risk Statements ]

26/27/28-36/37/38-48/23/25-50/53
[Safety Statements ]

26-28-36/37-45-61
[RIDADR ]

UN2811 - class 6.1 - PG 3 - EHS - Toxic solids, organic, n.o.s., HI: all
[WGK Germany ]

3
[Storage Class]

6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
[Hazard Classifications]

Acute Tox. 2 Dermal
Acute Tox. 3 Oral
Acute Tox. 4 Inhalation
Aquatic Chronic 2
Eye Irrit. 2
Skin Irrit. 2
STOT RE 1
STOT SE 3
Hazard InformationBack Directory
[Uses]

Catalyst for:
  • Addition polymerization reactions
  • Double carbonylation
  • Cyclization
  • Cyclometalation
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
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