| Identification | Back Directory | [Name]
2,2,2-TRICHLORO-1,1-DIMETHYLETHYL CHLOROFORMATE | [CAS]
66270-36-8 | [Synonyms]
TCBOC-CHLORIDE
β,β,β-trichloro-tert-butyl chloroformate
2,2,2-trichloro-1,1-dimethyl chloroformate
β,β,β-trichloro-tert-butoxycarbonyl chloride
2,2,2-trichloro-1,1-dimethyethyl chloroformate
2,2,2-TRICHLORO-1,1-DIMETHYLETHYL CHLOROFORMATE
BETA,BETA,BETA-TRICHLORO-TERT-BUTYL CHLOROFORMATE
2,2,2-Trichloro-1,1-diMethylethyl chloroforMate 96%
1,1,1-trichloro-2-Methylpropan-2-yl carbonochloridate
BETA,BETA,BETA-TRICHLORO-TERT-BUTOXYCARBONYL CHLORIDE
Chloridocarbonic acid 2,2,2-trichloro-1,1-dimethylethyl ester
Carbonochloridic acid, 2,2,2-trichloro-1,1-dimethylethyl ester
TCBoc-chloride, β,β,β-Trichloro-tert-butoxycarbonyl chloride
TCBoc-chloride, β,β,β-Trichloro-tert-butyl chloroformate, β,β,β-Trichloro-tert-butoxycarbonyl chloride | [EINECS(EC#)]
266-293-4 | [Molecular Formula]
C5H6Cl4O2 | [MDL Number]
MFCD00000801 | [MOL File]
66270-36-8.mol | [Molecular Weight]
239.91 |
| Chemical Properties | Back Directory | [Melting point ]
28-30 °C(lit.)
| [Boiling point ]
83-84 °C14 mm Hg(lit.)
| [density ]
1.4953 (estimate) | [storage temp. ]
2-8°C | [solubility ]
ethanol: soluble10%, clear, colorless | [form ]
solid | [BRN ]
1935464 | [InChI]
InChI=1S/C5H6Cl4O2/c1-4(2,5(7,8)9)11-3(6)10/h1-2H3 | [InChIKey]
GMELMFSDPDSXOZ-UHFFFAOYSA-N | [SMILES]
C(Cl)(OC(C)(C)C(Cl)(Cl)Cl)=O |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
23/24/25-34 | [Safety Statements ]
26-36/37/39-45 | [RIDADR ]
UN 2928 6.1/PG 2
| [WGK Germany ]
3
| [F ]
4.5-10-19-21 | [HazardClass ]
6.1(a) | [PackingGroup ]
II | [Storage Class]
6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials | [Hazard Classifications]
Acute Tox. 3 Oral
Skin Corr. 1B |
| Hazard Information | Back Directory | [Uses]
Used as easily removable acid- and base-stable protecting group for nitrogen, including amino acids and nucleosides; protecting group for alcohols. | [General Description]
The solvolysis rate constants of 2,2,2-trichloro-1,1-dimethylethyl chloroformate in binary and pure solvents was studied. | [Synthesis]
2,2,2-Trichloro-t-butoxycarbonyl Chloride is prepared from trichloro-t-butanol with Phosgene1 or triphosgene (Bis(trichloromethyl) Carbonate) (eq 1).
 |
| Spectrum Detail | Back Directory | [Spectrum Detail]
2,2,2-TRICHLORO-1,1-DIMETHYLETHYL CHLOROFORMATE(66270-36-8)1HNMR
2,2,2-TRICHLORO-1,1-DIMETHYLETHYL CHLOROFORMATE(66270-36-8)Raman
2,2,2-TRICHLORO-1,1-DIMETHYLETHYL CHLOROFORMATE(66270-36-8)IR
2,2,2-TRICHLORO-1,1-DIMETHYLETHYL CHLOROFORMATE(66270-36-8)FT-IR
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| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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