| Identification | Back Directory | [Name]
1-TRIMETHYLSILOXY-1,3-BUTADIENE | [CAS]
6651-43-0 | [Synonyms]
1-TRIMETHYLSILOXY-1,3-BUTADIENE
1-TRIMETHYLSILYLOXY-1,3-BUTADIENE
4-(Trimethylsiloxy)-1,3-butadiene
Trimethyl(1,3-butadienyloxy)silane
(1,3-Butadienyloxy)trimethylsilane
Trimethylsilyl 1,3-butadienyl ether
1,3-Butadienyl(trimethylsilyl) ether
Silane, (1,3-butadienyloxy)trimethyl-
1-(TriMethylsiloxy)-1,3-butadiene 98%
(E)-(buta-1,3-dien-1-yloxy)triMethylsilane
1-(Trimethylsilyloxy)-1,3-butadiene, mixture of isomers, 98%
1-(TRIMETHYLSILYLOXY)-1,3-BUTADIENE, 98% , MIXTURE OF ISOMERS | [Molecular Formula]
C7H14OSi | [MDL Number]
MFCD00009647 | [MOL File]
6651-43-0.mol | [Molecular Weight]
142.27 |
| Chemical Properties | Back Directory | [Appearance]
clear light yellow liquid | [Boiling point ]
131 °C(lit.)
| [density ]
0.811 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.448(lit.)
| [Fp ]
77 °F
| [storage temp. ]
2-8°C
| [solubility ]
Sol most standard organic solvents. | [form ]
liquid | [Specific Gravity]
0.811 | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [BRN ]
1902024 | [InChI]
1S/C7H14OSi/c1-5-6-7-8-9(2,3)4/h5-7H,1H2,2-4H3/b7-6+ | [InChIKey]
UQGOYQLRRBTVFM-VOTSOKGWSA-N | [SMILES]
C[Si](C)(C)O\C=C\C=C |
| Hazard Information | Back Directory | [Chemical Properties]
clear light yellow liquid | [Uses]
Diene used in the Diels-Alder reaction. | [Physical properties]
bp 131 °C, bp 49.5 °C/25 mmHg; d 0.811 g cm?3. | [General Description]
Mechanism of Diels-Alder reaction between 1-(trimethylsiloxy)-1,3-butadiene and 4,6-dinitrobenzofuroxan has been studied using state-of-the-art computational methods. | [Purification Methods]
Purify it by fractional distillation and collect the fractions with the required 1H NMR. Store it under N2 — it is a flammable and moisture-sensitive liquid. [Caseau et al. Bull Soc Chim Fr 16658 1972, Belge Patent 670,769, Chem Abstr 65 5487d 1966.] |
|
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Sigma-Aldrich
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