666826-16-0

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666826-16-0 Structure

Identification	Back Directory
[Name] Bis(1,5-cyclooctadiene)iridium(I)tetrakis[3,5-bis(trifluoromethyl)phenyl]borate,98%
[CAS] 666826-16-0
[Synonyms] Bis(1,5-cyclooctadiene)iridium tetrakis[3,5-bis(trifluoromethyl) BIS(CYCLOOCTADIENE)IRIDIUM(I)(TETRAKIS-[3,5-BIS(TRIFLUORMETHYL)PHENYL]BORATE) Bis(cyclooctadiene)iridium(Ⅰ) (tetrakis-[3,5-bis(trifluormethyl)phenyl]borate) Bis(1,5-cyclooctadiene)iridium(I)tetrakis[3,5-bis(trifluoromethyl)phenyl]borate,98% Bis(1,5-cyclooctadiene)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, 98% (1Z,5Z)-cycloocta-1,5-diene:iridium:tetrakis[3,5-bis(trifluoromethyl)phenyl]boranuide Bis(1,5-cyclooctadiene)iridium(I)tetrakis[3,5-bis(trifluoromethyl)phenyl]borate,98% ISO 9001：2015 REACH
[Molecular Formula] Ir(COD)2BARF
[MDL Number] MFCD10567389
[MOL File] 666826-16-0.mol

Chemical Properties	Back Directory
[storage temp. ] under inert gas (nitrogen or Argon) at 2-8°C
[form ] crystal
[color ] black
[InChIKey] YQXKTVMJDKWGHI-AUUWQFPRSA-N
[SMILES] [Ir+].C1CC=CCCC=C1.C2CC=CCCC=C2.FC(F)(F)c3cc(cc(c3)C(F)(F)F)[B-](c4cc(cc(c4)C(F)(F)F)C(F)(F)F)(c5cc(cc(c5)C(F)(F)F)C(F)(F)F)c6cc(cc(c6)C(F)(F)F)C(F)(F)F

Safety Data	Back Directory
[Hazard Codes ] Xi
[Risk Statements ] 36/37/38
[Safety Statements ] 26
[WGK Germany ] 3
[HS Code ] 28439000
[Storage Class] 11 - Combustible Solids

Hazard Information	Back Directory
[Uses] Catalyst for: Asymmetric hydrogenation reactions Directed cyclodehydration reaction Direct prenylation via C-H oxidative addition-allene insertion Double intramolecular hydroalkoxylation Intramolecular hydroamination reactions Directed C-H bond cleavage Imine vinylation reactions Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
[reaction suitability] core: iridium reagent type: catalyst

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