| Identification | Back Directory | [Name]
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE | [CAS]
69227-47-0 | [Synonyms]
TRI(3,5-XYLYL)PHOSPHINE
Tris(3,5-dimethylphenyl)
TRIS(3,5-XYLYL)PHOSPHINE
Trisdimethylphenylphosphine
Tri(3,5-dimethylphenyl)phosphine
tris(3,5-dimethylphenyl)-phosphin
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
tris(3,5-dimethylphenyl)phosphane
Phosphine, tris(3,5-dimethylphenyl)-
Tris(3,5-dimethylphenyl)phosphine,98%
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE, 97+%
Tris(3,5-dimethylphenyl)phosphineTris(3,5-xylyl)phosphine | [EINECS(EC#)]
624-162-2 | [Molecular Formula]
C24H27P | [MDL Number]
MFCD03094579 | [MOL File]
69227-47-0.mol | [Molecular Weight]
346.44 |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
161-164 °C
| [Boiling point ]
474.1±45.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
crystal | [color ]
white | [InChI]
1S/C24H27P/c1-16-7-17(2)11-22(10-16)25(23-12-18(3)8-19(4)13-23)24-14-20(5)9-21(6)15-24/h7-15H,1-6H3 | [InChIKey]
XRALRSQLQXKXKP-UHFFFAOYSA-N | [SMILES]
Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3 | [EPA Substance Registry System]
Phosphine, tris(3,5-dimethylphenyl)- (69227-47-0) |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
Catalyst for:
- Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones
- Highly selective rhodium-catalyzed hydrogenation reactions
- Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes
Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes
Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
22 | [Safety Statements ]
26-36/37/39-22 | [WGK Germany ]
3 | [TSCA ]
Yes | [HS Code ]
29310099 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
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www.energy-chemical.com |
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T&W GROUP
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www.trustwe.com/ |
| Company Name: |
Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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