| Identification | Back Directory | [Name]
BORANE-TERT-BUTYLAMINE COMPLEX | [CAS]
7337-45-3 | [Synonyms]
NSC 114045 butylamineborane T-BUTYLAMINE BORANE tert-Butylaminebrane TERT-BUTYLAMINE BORANE BORANE-TERT-BUTYLAMINE t-butylamineborane,tbab BORANE, T-BUTYLAMINE COMPLEX BORON HYDRIDE TERT-BUTYLAMINE BORANE-TERT-BUTYLAMINE COMPLEX (tert-butylamine)trihydroboron Borance-tert-ButylaMine coMplex tert-butylamine,compd.withbh3(1:1) tert-butylamine,compd.withborane(1:1) Trihydro(2-methyl-2-propanamine) boron Borane-tert-butylamine complex, pellets 2-methyl-2-propanamin compd. with borane 2-methyl-2-propanamine compd. with borane Borane,t-butylaminecomplex,powder,min.97% 2-methyl-2-propanamincompd.withborane(1:1) 2-methyl-2-propanaminecompd.withborane(1:1) Borane-tert-butylamine complex, 95%, powder Boron hydride-tert-butylamine for synthesis BORANE-TERT-BUTYLAMINE COMPLEX, POWDER, 97% Boranetbutylaminecomplexpowderminwhitepowder 2-Propanamine,2-methyl-,compd.withborane(1:1) trihydro(2-methyl-2-propanamine)-,(T-4)-Boron Borane, t-butylamine complex, powder, min. 97% Boron, trihydro(2-methyl-2-propanamine)-, (T-4)- Borane-tert-butylaMine coMplex, powder, 95% 25GR Borane tert-butylamine complex,tert-Butylamine borane BORANE-TERT-BUTYLAMINE COMPLEX, PELLETS, 11MM DIAM., 97% | [EINECS(EC#)]
230-851-5 | [Molecular Formula]
C4H14BN | [MDL Number]
MFCD00075635 | [MOL File]
7337-45-3.mol | [Molecular Weight]
86.97 |
| Chemical Properties | Back Directory | [Appearance]
white to off-white fine crystalline powder | [Melting point ]
98-100 °C (dec.)(lit.)
| [density ]
0,87 g/cm3 | [storage temp. ]
Refrigerator | [solubility ]
27g/l | [form ]
powder
| [color ]
White to off-white | [Water Solubility ]
Soluble in water (27 g/L at 20°C) and methanol. | [BRN ]
4134905 | [InChI]
InChI=1S/C4H11N.BH3/c1-4(2,3)5;/h5H2,1-3H3;1H3 | [InChIKey]
GKFJEDWZQZKYHV-UHFFFAOYSA-N | [SMILES]
N([H])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H].B | [EPA Substance Registry System]
Boron, trihydro(2-methyl-2-propanamine)-, (T-4)- (7337-45-3) |
| Hazard Information | Back Directory | [Chemical Properties]
white to off-white crystalline powder | [Uses]
Reactant involved in:
Non-destructive analyses and conservation treatments of Indian drawings;
Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes;
The formation of σ-borane complexes;
Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins;
Photochemical hydroboration and oxidation of single-walled carbon nanotubes | [Application]
Borane tert-butylamine (BTB) complex may be used as strong co-reducing agent in the following syntheses: copper (I) oxide nanoparticles diphosphine-protected gold nanocluster 4-acetoxycinnamyl alcohols Reactant involved in: Non-destructive analyses and conservation treatments of Indian drawings Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes The formation of σ-borane complexes Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins Photochemical hydroboration and oxidation of single-walled carbon nanotubes | [General Description]
Borane tert-butylamine complex is a mild reducing agent. It participates in the selective reduction of aldehydes and ketones to corresponding alcohol. It takes part as a reducing agent in the synthesis of monodisperse palladium nanoparticles (Pd NPs), monodisperse gold (Au) nanoparticles and carbon-supported Pd electrocatalysts. | [reaction suitability]
reagent type: reductant |
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