ChemicalBook--->CAS DataBase List--->7337-45-3

7337-45-3

7337-45-3 Structure

7337-45-3 Structure
IdentificationBack Directory
[Name]

BORANE-TERT-BUTYLAMINE COMPLEX
[CAS]

7337-45-3
[Synonyms]

NSC 114045
butylamineborane
T-BUTYLAMINE BORANE
tert-Butylaminebrane
TERT-BUTYLAMINE BORANE
BORANE-TERT-BUTYLAMINE
t-butylamineborane,tbab
BORANE, T-BUTYLAMINE COMPLEX
BORON HYDRIDE TERT-BUTYLAMINE
BORANE-TERT-BUTYLAMINE COMPLEX
(tert-butylamine)trihydroboron
Borance-tert-ButylaMine coMplex
tert-butylamine,compd.withbh3(1:1)
tert-butylamine,compd.withborane(1:1)
Trihydro(2-methyl-2-propanamine) boron
Borane-tert-butylamine complex, pellets
2-methyl-2-propanamin compd. with borane
2-methyl-2-propanamine compd. with borane
Borane,t-butylaminecomplex,powder,min.97%
2-methyl-2-propanamincompd.withborane(1:1)
2-methyl-2-propanaminecompd.withborane(1:1)
Borane-tert-butylamine complex, 95%, powder
Boron hydride-tert-butylamine for synthesis
BORANE-TERT-BUTYLAMINE COMPLEX, POWDER, 97%
Boranetbutylaminecomplexpowderminwhitepowder
2-Propanamine,2-methyl-,compd.withborane(1:1)
trihydro(2-methyl-2-propanamine)-,(T-4)-Boron
Borane, t-butylamine complex, powder, min. 97%
Boron, trihydro(2-methyl-2-propanamine)-, (T-4)-
Borane-tert-butylaMine coMplex, powder, 95% 25GR
Borane tert-butylamine complex,tert-Butylamine borane
BORANE-TERT-BUTYLAMINE COMPLEX, PELLETS, 11MM DIAM., 97%
[EINECS(EC#)]

230-851-5
[Molecular Formula]

C4H14BN
[MDL Number]

MFCD00075635
[MOL File]

7337-45-3.mol
[Molecular Weight]

86.97
Chemical PropertiesBack Directory
[Appearance]

white to off-white fine crystalline powder
[Melting point ]

98-100 °C (dec.)(lit.)
[density ]

0,87 g/cm3
[storage temp. ]

Refrigerator
[solubility ]

27g/l
[form ]

powder
[color ]

White to off-white
[Water Solubility ]

Soluble in water (27 g/L at 20°C) and methanol.
[BRN ]

4134905
[InChI]

InChI=1S/C4H11N.BH3/c1-4(2,3)5;/h5H2,1-3H3;1H3
[InChIKey]

GKFJEDWZQZKYHV-UHFFFAOYSA-N
[SMILES]

N([H])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H].B
[EPA Substance Registry System]

Boron, trihydro(2-methyl-2-propanamine)-, (T-4)- (7337-45-3)
Hazard InformationBack Directory
[Chemical Properties]

white to off-white crystalline powder
[Uses]

Reactant involved in: Non-destructive analyses and conservation treatments of Indian drawings; Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes; The formation of σ-borane complexes; Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins; Photochemical hydroboration and oxidation of single-walled carbon nanotubes
[Application]

Borane tert-butylamine (BTB) complex may be used as strong co-reducing agent in the following syntheses:
copper (I) oxide nanoparticles
diphosphine-protected gold nanocluster
4-acetoxycinnamyl alcohols
Reactant involved in:
Non-destructive analyses and conservation treatments of Indian drawings
Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes
The formation of σ-borane complexes
Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins
Photochemical hydroboration and oxidation of single-walled carbon nanotubes
[General Description]

Borane tert-butylamine complex is a mild reducing agent. It participates in the selective reduction of aldehydes and ketones to corresponding alcohol. It takes part as a reducing agent in the synthesis of monodisperse palladium nanoparticles (Pd NPs), monodisperse gold (Au) nanoparticles and carbon-supported Pd electrocatalysts.
[reaction suitability]

reagent type: reductant
Safety DataBack Directory
[Symbol(GHS) ]

Skull and Crossbones (GHS06)Environment (GHS09)
GHS06,GHS09
[Signal word ]

Danger
[Hazard statements ]

H301+H311-H315-H319-H411
[Precautionary statements ]

P264-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338
[Hazard Codes ]

T
[Risk Statements ]

21-25-36/37/38
[Safety Statements ]

26-36/37-45
[RIDADR ]

UN 2811 6.1/PG 3
[WGK Germany ]

3
[RTECS ]

EO3900000
[F ]

9
[TSCA ]

Yes
[HazardClass ]

4.1
[PackingGroup ]

III
[HS Code ]

29299090
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 3 Dermal
Acute Tox. 3 Oral
Aquatic Chronic 2
Eye Irrit. 2
Skin Irrit. 2
Spectrum DetailBack Directory
[Spectrum Detail]

BORANE-TERT-BUTYLAMINE COMPLEX(7337-45-3)MS
BORANE-TERT-BUTYLAMINE COMPLEX(7337-45-3)1HNMR
BORANE-TERT-BUTYLAMINE COMPLEX(7337-45-3)13CNMR
BORANE-TERT-BUTYLAMINE COMPLEX(7337-45-3)IR1
BORANE-TERT-BUTYLAMINE COMPLEX(7337-45-3)IR2
BORANE-TERT-BUTYLAMINE COMPLEX(7337-45-3)Raman
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