| Identification | Back Directory | [Name]
BIS(3,5-DIMETHYLPHENYL)CHLOROPHOSPHINE | [CAS]
74289-57-9 | [Synonyms]
BIS(3,5-DIMETHYLPHENYL)CHLOROPHOSPHINE
Chlorobis(3,5-dimethylphenyl)phosphine
chloro-bis(3,5-dimethylphenyl)phosphane
Bis(3,5-dimethylphenyl)phosphine chloride
Bis(3,5-dimethylphenyl)chlorophosphine,98%
Bis(3,5-dimethylphenyl)phosphinous chloride
Bis(3,5-dimethylphenyl)chlorophosphine, tech.
Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%
Phosphinous chloride, P,P-bis(3,5-dimethylphenyl)- | [EINECS(EC#)]
636-136-8 | [Molecular Formula]
C16H18ClP | [MDL Number]
MFCD01630841 | [MOL File]
74289-57-9.mol | [Molecular Weight]
276.74 |
| Chemical Properties | Back Directory | [Boiling point ]
115-135 °C(Press: 0.015 Torr) | [density ]
1.102 g/mL at 25 °C | [refractive index ]
n20/D 1.606 | [Fp ]
110 °C | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
liquid | [Appearance]
Colorless to light yellow Liquid | [Water Solubility ]
Reacts with water. | [Sensitive ]
Moisture Sensitive | [InChI]
1S/C16H18ClP/c1-11-5-12(2)8-15(7-11)18(17)16-9-13(3)6-14(4)10-16/h5-10H,1-4H3 | [InChIKey]
FCEBDAANWYNQMO-UHFFFAOYSA-N | [SMILES]
Cc1cc(C)cc(c1)P(Cl)c2cc(C)cc(C)c2 |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
34 | [Safety Statements ]
26-36/37/39-43-45 | [RIDADR ]
UN3261 | [WGK Germany ]
3 | [HazardClass ]
8 | [PackingGroup ]
II | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Hazard Information | Back Directory | [Uses]
Chlorobis(3,5-dimethylphenyl)phosphine is used in the synthesis of (S)- and (R)-2,2?-Bis[bis(3,5-dimethylphenyl)phosphinoyl]-5,5?,6,6?,7,7?,8,8?-octahydro-1,1?-binaphthyl (Xyl-H 8 -BINAPO). | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
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