| Identification | Back Directory | [Name]
N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE | [CAS]
7688-51-9 | [Synonyms]
Einecs 231-699-2
Allylbis(trimethylsilyl)amine
N,N'-bis(trimethylsilyl)allylamine
N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE
Prop-2-en-1-ylbis(trimethylsilyl)amine
N-Allyl-N,N-bis(trimethylsilyl)amine 97%
N,N-bis(trimethylsilyl)prop-2-en-1-amine
2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN&
N-allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine
1,1,1-Trimethyl-N-2-propenyl-N-(trimethylsilyl)silanamine
α,α,α-Trimethyl-N-(2-propenyl)-N-(trimethylsilyl)silanamine
Silanamine, 1,1,1-trimethyl-N-2-propen-1-yl-N-(trimethylsilyl)- | [EINECS(EC#)]
231-699-2 | [Molecular Formula]
C9H23NSi2 | [MDL Number]
MFCD00545193 | [MOL File]
7688-51-9.mol | [Molecular Weight]
201.46 |
| Chemical Properties | Back Directory | [Boiling point ]
72 °C/15 mmHg (lit.) | [density ]
0.816 g/mL at 25 °C (lit.) | [refractive index ]
n20/D 1.440(lit.) | [Fp ]
109 °F | [form ]
liquid | [Specific Gravity]
0.817 | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [InChI]
1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3 | [InChIKey]
CVNCFZIIZGNVFD-UHFFFAOYSA-N | [SMILES]
C[Si](C)(C)N(CC=C)[Si](C)(C)C |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
10-36/37/38 | [Safety Statements ]
16-26-36/37 | [RIDADR ]
UN 1993 3/PG 3 | [WGK Germany ]
3 | [TSCA ]
TSCA listed | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:
- Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
- Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
- Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.
AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive. |
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| Company Name: |
Sigma-Aldrich
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| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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