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7783-57-5

7783-57-5 Structure

7783-57-5 Structure
IdentificationBack Directory
[Name]

THALLIUM(III) FLUORIDE
[CAS]

7783-57-5
[Synonyms]

TlF3
TG MIX 11
thallium trifluoride
THALLIUM (IC) FLUORIDE
THALLIUM FLUORIDE (IC)
THALLIUM(III) FLUORIDE
thalliumfluoride(tlf3)
Thallium fluoride (TlF3)
Thallium(III)fluoride99%
THALLIUM(III)TRIFLUORIDE
THALLIUM(III) FLUORIDE 99%
[EINECS(EC#)]

232-010-8
[Molecular Formula]

F3Tl
[MDL Number]

MFCD00067513
[MOL File]

7783-57-5.mol
[Molecular Weight]

261.38
Chemical PropertiesBack Directory
[Melting point ]

550 °C (dec.)(lit.)
[Boiling point ]

655
[density ]

8.36 g/mL at 25 °C(lit.)
[solubility ]

reacts with H2O
[form ]

white orthorhombic crystals
[color ]

white orthorhombic crystals, crystalline; hygroscopic
[Water Solubility ]

insoluble H2O [KIR83]
[crystal system]

Nogata
[Space group]

Pm2a
[Lattice constant]

a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.518480.60980.519169090900.1641
[EPA Substance Registry System]

Thallium fluoride (TlF3) (7783-57-5)
Hazard InformationBack Directory
[Chemical Properties]

olive green ortho-rhomb crystal(s); very sensitive to moisture; quickly decomposed by water; decomposed if heated in air [MER06] [KIR83]
[Preparation]

The fluorination of Thallium(III) fluoride Ti2Cl3 is accomplished in an apparatus consisting of a quartz reaction tube containing a quartz boat with the reagent. The fluorine gas is introduced via a 3-m.-long copper capillary which permits rotation of the reaction tube through a 90° angle. The reaction begins even at room temperature.
2T22O3+ 6F2 = 4TiF3 + 3O2
Safety DataBack Directory
[Hazard Codes ]

T+,N,T
[Risk Statements ]

26/28-33-51/53
[Safety Statements ]

13-28-45-61
[RIDADR ]

UN 1707 6.1/PG 2
[WGK Germany ]

3
[Hazard Note ]

Toxic
[TSCA ]

TSCA listed
[HazardClass ]

6.1(a)
[PackingGroup ]

II
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