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78948-87-5

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78948-87-5 Structure

78948-87-5 Structure
IdentificationBack Directory
[Name]

MONOPEROXYPHTHALIC ACID MAGNESIUM SALT, HEXAHYDRATE
[CAS]

78948-87-5
[Synonyms]

MMPP
H-48
Interox H-48
MAGNESIUMMONOPEROXYPHTHALATETECH
Bis(2-carboxybenzoyldioxy)magnesium
Magnesiumbis(monoperoxyphthalate)hexahydrate
Magnesiummonoperoxyphthalatehexahydrate,tech.ca80%
Magnesium monoperoxyphthalate hexahydrate., tech, ca 80%
dihydrogen bis[monoperoxyphthalato(2-)-O1,OO1]magnesate(2-)
Magnesium Monoperoxyphthalate Magnesium Bis(monoperoxyphthalate) MMPP
Magnesate(2-), bis2-carboxybenzenecarboperoxoato(2-)-.kappa.O,.kappa.OO-, dihydrogen, (T-4)-
[EINECS(EC#)]

279-013-0
[Molecular Formula]

C16H20MgO16-2
[MDL Number]

MFCD00013096
[MOL File]

78948-87-5.mol
[Molecular Weight]

492.625
Chemical PropertiesBack Directory
[Melting point ]

93°C (dec.)
[density ]

1.62[at 20℃]
[vapor pressure ]

18.4Pa at 20℃
[Water Solubility ]

291g/L at 20℃
[InChI]

1S/2C8H6O5.Mg.6H2O/c2*9-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h2*1-4,12H,(H,9,10);;6*1H2/q;;+2;;;;;;/p-2
[InChIKey]

WWOYCMCZTZTIGU-UHFFFAOYSA-L
[SMILES]

O.O.O.O.O.O.OOC(=O)c1ccccc1C(=O)O[Mg]OC(=O)c2ccccc2C(=O)OO
[LogP]

-1.47 at 20℃
Safety DataBack Directory
[Risk Statements ]

8-36/37/38
[Safety Statements ]

17-26-27-36/37/39
[RIDADR ]

1479
[WGK Germany ]

WGK 1
[REACH Registrations]

Active
[Storage Class]

5.2 - Organic peroxides and self-reacting hazardous materials
[Hazard Classifications]

Acute Tox. 4 Inhalation
Eye Dam. 1
Org. Perox. E
Skin Corr. 1C
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

2-Bromo-1-[4-(methylsulfonyl)phenyl]-1-ethanone
Hazard InformationBack Directory
[Uses]

Reagent for:
  • Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
  • Oxidation rections under mild conditions
  • Epoxidation of unsaturated steroids
  • Synthesis of ring-B oxygenated steroids as anticancer agents
[General Description]

This product MMPP is an alternative to widely used oxidant MCPBA as it is cheap, stable in the solid state, safer in handling and easier to use and thus aligns with the principle "Designing Safer Chemicals".
Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones.
Magnesium Bis(monoperoxyphthalate) Hexahydrate (MMPP).
Highly efficient epoxidation of unsaturated steroids using magnesium bis(monoperoxyphthalate) hexahydrate.
[Flammability and Explosibility]

Notclassified
[reaction suitability]

reagent type: oxidant
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