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795290-34-5

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795290-34-5 Structure

795290-34-5 Structure
IdentificationBack Directory
[Name]

(1S,1μS,2R,2μR)-2,2μ-Di-tert-butyl-2,3,2μ,3μ-tetrahydro-1H,1μH(1,1μ)biisophosphindolyl
[CAS]

795290-34-5
[Synonyms]

(1S,1μS,2R,2μR)-DuanPhos
(1S,1'S,2R,2'R)-2,2'-Di-tert-butyl-2,2',3,3'-tetrahydro-1H,1'H-1,1'-biisophosphindole
(1S,1'S,2R,2'R)-2,2'-Di-tert-butyl-2,2',3,3'-tetrahydro-1H,1'H-1,1'-biiSophosphindole
(1S,1μS,2R,2μR)-2,2μ-Di-tert-butyl-2,3,2μ,3μ-tetrahydro-1H,1μH(1,1μ)biisophosphindolyl
(1S,1'S,2R,2'R)-2,2'-bis(1,1-diMethylethyl)-2,2',3,3'-tetrahydro-,1,1'-Bi-1H-isophosphindole
1,1'-Bi-1H-isophosphindole, 2,2'-bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-, (1S,1'S,2R,2'R)-
(1S,1'S,2R,2'R)-2,2'-Bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-1,1'-bi-1H-isophosphindole,99%e.e.
[Molecular Formula]

C24H32P2
[MDL Number]

MFCD11045432
[MOL File]

795290-34-5.mol
[Molecular Weight]

382.46
Chemical PropertiesBack Directory
[Melting point ]

215-226 °C
[Boiling point ]

474.5±45.0 °C(Predicted)
[form ]

solid
[InChI]

1S/C24H32P2/c1-23(2,3)25-15-17-11-7-9-13-19(17)21(25)22-20-14-10-8-12-18(20)16-26(22)24(4,5)6/h7-14,21-22H,15-16H2,1-6H3/t21-,22-,25+,26+/m0/s1
[InChIKey]

HCBRTCFUVLYSKU-CNXCYTMISA-N
[SMILES]

[H][C@]([C@@]1([H])[P@](C(C)(C)C)CC2=C1C=CC=C2)([P@](C(C)(C)C)C3)C4=C3C=CC=C4
Safety DataBack Directory
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

  • Ligand in rhodium-catalyzed ketone hydroacylation
  • Cocatalyst for highly selective rhodium-catalyzed conjugate addition reactions of 4-oxobutenamides with arylboronic acids
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