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804565-39-7

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804565-39-7 Structure

804565-39-7 Structure
IdentificationBack Directory
[Name]

Potassium (E)-propenyl-1-trifluoroborate
[CAS]

804565-39-7
[Synonyms]

(e)-propenyl-1-trifluoroborate
trifluoro-[(E)-prop-1-enyl]boranuide
Potassium (E)-trifluoro(1-propenyl)borate
Potassium trifluoro(prop-1-en-1-yl)borate
Potassium trans-1-propenyltrifluoroborate
potassiuM (E)-trifluoro(prop-1-enyl)borate
PotassiuM (E)-1-propenyl-1-trifluoroborate
potassium trifluoro(prop-1-en-1-yl)boranuide
PotassiuM (E)-trifluoro(prop-1-en-1-yl)borate
potassium,trifluoro-[(E)-prop-1-enyl]boranuide
[Molecular Formula]

C3H5BF3K
[MDL Number]

MFCD09992882
[MOL File]

804565-39-7.mol
[Molecular Weight]

147.976
Chemical PropertiesBack Directory
[Melting point ]

81-85°C
[form ]

solid
[InChI]

1S/C3H5BF3.K/c1-2-3-4(5,6)7;/h2-3H,1H3;/q-1;+1/b3-2+;
[InChIKey]

RLDWVFWDURMTAV-SQQVDAMQSA-N
[SMILES]

[K+].C\C=C\[B-](F)(F)F
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

37/38-41
[Safety Statements ]

26-39
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

Potassium?trans-1-propenyltrifluoroborate can be used:
  • As a substrate in the cross-coupling reactions with 2-(chloromethyl)-2,1-borazaronaphthalenes to yield allyl borazaronaphthalenes using a palladium catalyst.
  • In the synthesis of anethole dithiolethione-NH2 (ADT-NH2), which in turn is used to prepare a drug-H2S delivery system.
  • To prepare methyl (E)-2,2-dimethyl-5-(propen-1-yl)-4H-benzo[d][1,3]dioxine-7-carboxylate, a key intermediate for the synthesis of the alkaloid ampullosine.
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