ChemicalBook--->CAS DataBase List--->83194-70-1

83194-70-1

83194-70-1 Structure

83194-70-1 Structure
IdentificationBack Directory
[Name]

2,6-diMethyl-4-hydroxybenzoic acid Methyl ester
[CAS]

83194-70-1
[Synonyms]

2,6-diMethyl-4-hydroxybenzoic acid Methyl ester
4-Hydroxy-2,6-dimethylbenzoic acid methyl ester
Benzoic acid, 4-hydroxy-2,6-dimethyl-, methyl ester
[Molecular Formula]

C10H12O3
[MDL Number]

MFCD13191754
[MOL File]

83194-70-1.mol
[Molecular Weight]

180.2
Chemical PropertiesBack Directory
[Boiling point ]

285.1±35.0 °C(Predicted)
[density ]

1.138±0.06 g/cm3(Predicted)
[storage temp. ]

Sealed in dry,Room Temperature
[pka]

8.60±0.23(Predicted)
[Appearance]

Brown to black Solid
Spectrum DetailBack Directory
[Spectrum Detail]

2,6-diMethyl-4-hydroxybenzoic acid Methyl ester(83194-70-1)1HNMR
Hazard InformationBack Directory
[Synthesis]

Benzoic acid, 2,6-dimethyl-4-(phenylmethoxy)-, methyl ester

306297-02-9

2,6-diMethyl-4-hydroxybenzoic acid Methyl ester

83194-70-1

Step B: Benzyl protected phenol (8.5 g, 32 mmol) and Pd/C catalyst (750 mg, 10 wt% Pd) were dissolved in methanol (CH3OH). The solution was placed in a Parr reactor and the reaction was oscillated at 25°C for 17 h at a hydrogen pressure of 50 psi. Upon completion of the reaction, the catalyst was removed by diatomaceous earth filtration. The filtrate was concentrated to give 5.6 g (98% yield) of phenol as a white solid.

[References]

[1] Patent: US6391865, 2002, B1. Location in patent: Page column 41
[2] Patent: EP1175401, 2005, B1. Location in patent: Page/Page column 27
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