| Identification | Back Directory | [Name]
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS | [CAS]
850444-36-9 | [Synonyms]
97% TANIAPHOS
(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane
(S)-1-Diphenylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene
(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-diMethylaMino) (2-diphenylphosphinophenyl)Methane TANIAPHOS
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-
diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
(SP)-1-[(S)-alpha-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene >=97%, optical purity ee: >=99%
Taniaphos SL-T001-2, (2R)-1-[(S)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene (acc to CAS) | [Molecular Formula]
C38H34NP2.C5H5.Fe | [MDL Number]
MFCD08561147 | [MOL File]
850444-36-9.mol | [Molecular Weight]
687.581 |
| Chemical Properties | Back Directory | [alpha ]
-312° ±15° (c 0.5, CHCl3) | [storage temp. ]
2-8°C | [form ]
Powder | [color ]
orange | [Stability:]
store cold | [InChIKey]
DEHRMLQYTSYVBC-ZCLNGFLVSA-N | [SMILES]
[Fe].[CH]1[CH][CH][CH][CH]1.CN(C)[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7 |
| Questions And Answer | Back Directory | [Reactions]
- Ligand for the Ru-catalyzed hydrogenation of $-ketoesters, enamides and itaconates.
- Ligand for Cu-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones.
- AgOAc-catalyzed asymmetric amination of glycine Schiff bases with azodicarboxylates.
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