| Identification | Back Directory | [Name]
(-)-IPC2B(ALLYL), 1M IN PENTANE | [CAS]
85116-38-7 | [Synonyms]
(-) - Ipc2B (allyl) borane
(-)-Ipc2B(allyl)borane solution
(-)-IPC2B(ALLYL), 1M IN PENTANE
(-)-Ipc2B(allyl)borane solution
(-)-B-Allyldiisopinocampheylborane solution
(-)-Ipc2B(allyl)borane solution 1 M in pentane
(-)-B-ALLYLDIISOPINOCAMPHEYLBORANE 1 M IN DIOXANE
Allylbis((1r,2s,3r,5r)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane
Borane, 2-propenylbis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-
prop-2-enyl-bis[(1R,3R,4S,5R)-4,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]borane | [Molecular Formula]
C23H39B | [MDL Number]
MFCD09038448 | [MOL File]
85116-38-7.mol | [Molecular Weight]
326.37 |
| Hazard Information | Back Directory | [Uses]
This allylboration reagent is a convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols. | [Preparation]
(-)-IPC2B(ALLYL), 1M IN PENTANE can be prepared in three steps from either (+)- or (-)-α-pinene (eq 1) .
 | [Reactions]
(-)-IPC2B(ALLYL), 1M IN PENTANE is most often used as the crude preparation in Et2O; however, reactions have also been conducted in CS2, CHCl3, CH2Cl2, toluene, and THF. | [Solubility in organics]
(-)-IPC2B(ALLYL), 1M IN PENTANE is most often used as the crude preparation in Et2O; however, reactions have also been conducted in CS2, CHCl3, CH2Cl2, toluene, and THF. |
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