ChemicalBook--->CAS DataBase List--->858971-43-4

858971-43-4

858971-43-4 Structure

858971-43-4 Structure
IdentificationBack Directory
[Name]

1,2-Bis(phenylsulfinyl)ethanepalladium(II)acetate,min.98%ChristinaWhiteCatalyst
[CAS]

858971-43-4
[Synonyms]

White Catalyst
1,2-Bis(phenylsulfinyl)ethane-palladium diacetate
1,2-Bis(phenylsulfinyl)ethane palladium(II) acetate
1,2-Bis(phenylsulfinyl)ethane Palladium(II) Diacetate
1,2-Bis(phenylsulfinyl)ethanepalladium(II) acetate, min. 98%
1,2-Bis(phenylsulfinyl)ethanepalladium(II) acetate,Christina White Catalyst,98%
1,2-Bis(phenylsulfinyl)ethanepalladium(II)acetate,min.98%ChristinaWhiteCatalyst
1,2-Bis(phenylsulfinyl)ethanepalladiuM(II) acetate,98% Christina White Catalyst
[Molecular Formula]

C14H14O2S2.C4H6O4Pd
[MDL Number]

MFCD09842752
[MOL File]

858971-43-4.mol
[Molecular Weight]

502.902
Chemical PropertiesBack Directory
[storage temp. ]

Freezer
[solubility ]

soluble in Chloroform
[form ]

Powder
[color ]

orange to brown
[Stability:]

store cold
[InChI]

1S/C14H14O2S2.2C2H4O2.Pd/c15-17(13-7-3-1-4-8-13)11-12-18(16)14-9-5-2-6-10-14;2*1-2(3)4;/h1-10H,11-12H2;2*1H3,(H,3,4);/q;;;+2/p-2
[InChIKey]

SNNYSJNYZJXIFE-UHFFFAOYSA-L
[SMILES]

CC(=O)O[Pd]OC(C)=O.O=S(CCS(=O)c1ccccc1)c2ccccc2
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

41
[Safety Statements ]

26-39
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

2930.90.2900
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Dam. 1
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst for allylic oxidation.
  2. Catalyst for oxidative Heck reactions.
  3. Catalyst for allylic alkylation.
  4. Catalyst for allylic amination. 
Reactions of 858971-43-4
Hazard InformationBack Directory
[Uses]

Macrolactonization via Hydrocarbon Oxidation
[Uses]

Efficient bis-sulfoxide-Pd(II) catalyst for intramolecular allylic C–H oxidation, sequential allylic C–H oxidation/vinylic C–H arylation, and allylic C–H amination.
[General Description]

This product has been enhanced for catalytic efficiency.
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: C-H Activation
Spectrum DetailBack Directory
[Spectrum Detail]

1,2-Bis(phenylsulfinyl)ethanepalladium(II)acetate,min.98%ChristinaWhiteCatalyst(858971-43-4)1HNMR
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