| Identification | Back Directory | [Name]
1,2-Bis(phenylsulfinyl)ethanepalladium(II)acetate,min.98%ChristinaWhiteCatalyst | [CAS]
858971-43-4 | [Synonyms]
White Catalyst
1,2-Bis(phenylsulfinyl)ethane-palladium diacetate
1,2-Bis(phenylsulfinyl)ethane palladium(II) acetate
1,2-Bis(phenylsulfinyl)ethane Palladium(II) Diacetate
1,2-Bis(phenylsulfinyl)ethanepalladium(II) acetate, min. 98%
1,2-Bis(phenylsulfinyl)ethanepalladium(II) acetate,Christina White Catalyst,98%
1,2-Bis(phenylsulfinyl)ethanepalladium(II)acetate,min.98%ChristinaWhiteCatalyst
1,2-Bis(phenylsulfinyl)ethanepalladiuM(II) acetate,98% Christina White Catalyst | [Molecular Formula]
C14H14O2S2.C4H6O4Pd | [MDL Number]
MFCD09842752 | [MOL File]
858971-43-4.mol | [Molecular Weight]
502.902 |
| Chemical Properties | Back Directory | [storage temp. ]
Freezer | [solubility ]
soluble in Chloroform | [form ]
Powder | [color ]
orange to brown | [Stability:]
store cold | [InChI]
1S/C14H14O2S2.2C2H4O2.Pd/c15-17(13-7-3-1-4-8-13)11-12-18(16)14-9-5-2-6-10-14;2*1-2(3)4;/h1-10H,11-12H2;2*1H3,(H,3,4);/q;;;+2/p-2 | [InChIKey]
SNNYSJNYZJXIFE-UHFFFAOYSA-L | [SMILES]
CC(=O)O[Pd]OC(C)=O.O=S(CCS(=O)c1ccccc1)c2ccccc2 |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
41 | [Safety Statements ]
26-39 | [WGK Germany ]
3 | [TSCA ]
No | [HS Code ]
2930.90.2900 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Dam. 1 |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for allylic oxidation.
- Catalyst for oxidative Heck reactions.
- Catalyst for allylic alkylation.
- Catalyst for allylic amination.
|
| Hazard Information | Back Directory | [Uses]
Macrolactonization via Hydrocarbon Oxidation | [Uses]
Efficient bis-sulfoxide-Pd(II) catalyst for intramolecular allylic C–H oxidation, sequential allylic C–H oxidation/vinylic C–H arylation, and allylic C–H amination. | [General Description]
This product has been enhanced for catalytic efficiency. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: C-H Activation |
|
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
TCI Europe
|
| Tel: |
320-37350700 |
| Website: |
https://www.tcichemicals.com/de/de/index.html |
| Company Name: |
TCI AMERICA
|
| Tel: |
800-4238616 |
| Website: |
https://www.tcichemicals.com/en/us/index.html |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Alfa Chemistry
|
| Tel: |
1-516-6625404 |
| Website: |
https://www.alfa-chemistry.com |
|