| Identification | Back Directory | [Name]
TRANS-2-(3-CHLOROPHENYL)VINYLBORONIC AC& | [CAS]
871125-84-7 | [Synonyms]
TRANS-2-(3-CHLOROPHENYL)VINYLBORONIC
TRANS-2-(3-CHLOROPHENYL)VINYLBORONIC AC&
E-2-(3-Chlorophenyl)vinylboronic acid,pinacol ester
3-chloro-trans-beta-styrylboronic acid pinacol ester
trans-2-(3-Chlorophenyl)vinylboronic acid pinacol ester 97%
(E)-2-(3-Chlorostyryl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
(E)-2-(3-chlorostyryl)-4,4,5,5-tetramethyl-1,3-dioxa-2-borolane
(E-2-(3-Chlorophenyl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-[(E)-2-(3-chlorophenyl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-[(1E)-2-(3-chlorophenyl)ethenyl]-4,4,5,5-tetramet hyl-1,3,2-dioxaborolane
1,3,2-Dioxaborolane, 2-[(1E)-2-(3-chlorophenyl)ethenyl]-4,4,5,5-tetramethyl- | [Molecular Formula]
C14H18BClO2 | [MDL Number]
MFCD08276867 | [MOL File]
871125-84-7.mol | [Molecular Weight]
264.56 |
| Chemical Properties | Back Directory | [Boiling point ]
138-140 °C0.9-1.0 mm Hg | [density ]
1.049 g/mL at 25 °C | [refractive index ]
n20/D 1.536 | [Fp ]
>230 °F | [storage temp. ]
2-8°C | [Appearance]
Light yellow to yellow Liquid | [InChI]
1S/C14H18BClO2/c1-13(2)14(3,4)18-15(17-13)9-8-11-6-5-7-12(16)10-11/h5-10H,1-4H3/b9-8+ | [InChIKey]
NZBKTAJNGYXYSQ-CMDGGOBGSA-N | [SMILES]
CC1(C)OB(OC1(C)C)\C=C\c2cccc(Cl)c2 |
| Hazard Information | Back Directory | [Uses]
trans-2-(3-Chlorophenyl)vinylboronic acid pinacol ester can be used as a reactant:
- To prepare aryl derivatives by C?C bond formation via palladium-catalyzed Suzuki?Miyaura reaction.
- In the diastereoselective synthesis of alkenes via K3PO4-promoted transition metal-free nucleophilic substitution of unactivated alkyl triflates.
- To synthesize (3-chlorophenyl)cyclopropyl boronic acid pinacol ester by reacting with diazomethane.
| [Uses]
E-2-(3-Chlorophenyl)vinylboronic acid, pinacol ester |
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