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886061-48-9

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886061-48-9 Structure

886061-48-9 Structure
IdentificationBack Directory
[Name]

Bis(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)copper(I) tetrafluoroborate
[CAS]

886061-48-9
[Synonyms]

1,3-bis[2,6-di(propan-2-yl)phenyl]imidazole:copper(1+):tetrafluoroborate
Bis(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)copper(I) tetrafluoroborate
Bis[1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene]copper tetrafluoroborate
[Molecular Formula]

C54H72BCuF4N4
[MDL Number]

MFCD11045422
[MOL File]

886061-48-9.mol
Chemical PropertiesBack Directory
[Melting point ]

>300 °C
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[form ]

powder
[Appearance]

White to off-white Solid
[InChI]

1S/2C27H37N2.BF4.Cu/c2*1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;2-1(3,4)5;/h2*9-21H,1-8H3;;/q;;-1;+1
[InChIKey]

CFCDDEHZQJMQJR-UHFFFAOYSA-N
[SMILES]

F[B-](F)(F)F.CC(C)c1cccc(C(C)C)c1N2C=CN(C2[Cu+]C3N(C=CN3c4c(cccc4C(C)C)C(C)C)c5c(cccc5C(C)C)C(C)C)c6c(cccc6C(C)C)C(C)C
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Catalyst for:
  • Double carbonylation reaction
  • Hydrosilylation reactions
[reaction suitability]

core: copper
reagent type: catalyst
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