ChemicalBook--->CAS DataBase List--->887-54-7

887-54-7

887-54-7 Structure

887-54-7 Structure
IdentificationBack Directory
[Name]

CHLORTHAL MONOMETHYL ESTER
[CAS]

887-54-7
[Synonyms]

MONOMETHY
dacthalmonoacid
Dacthal monoacid
chlorthal-monomethyl
CHLORTHAL MONOMETHYL ESTER
Methyl tetrachlorophthalate
MONOMETHYL TETRACHLOROTERE PHTHALATE
methyltetrachloroterephthalicacidester
Methyl 2,3,5,6-tetrachloroterephthalate
4-acetoxy-2,3,5,6-tetrachlorobenzoicacid
Tetrachloroterephthalic acid methyl ester
monomethyl2,3,5,6-tetrachloroterephthalate
Tetrachloroterephthalic acid, monomethyl ester
Terephthalic acid, tetrachloro-, monomethyl ester
2,3,5,6-Tetrachloro-4-(methoxycarbonyl)benzoic acid
Monomethyltetrachloroterephthalate @100 μg/mL in Acetone
2,3,5,6-Tetrachloro-1,4-benzenedicarboxylic Acid 4-Methyl Ester
1,4-Benzenedicarboxylic acid, 2,3,5,6-tetrachloro-, monomethyl ester
[Molecular Formula]

C9H4Cl4O4
[MDL Number]

MFCD00155379
[MOL File]

887-54-7.mol
[Molecular Weight]

317.94
Chemical PropertiesBack Directory
[Melting point ]

174-177°C
[Boiling point ]

429.1±45.0 °C(Predicted)
[density ]

1.694±0.06 g/cm3(Predicted)
[storage temp. ]

Refrigerator
[solubility ]

DMSO, Methanol (Slightly)
[form ]

Solid
[pka]

0.27±0.32(Predicted)
[color ]

White to Pale Beige
[EPA Substance Registry System]

Chlorthal-monomethyl (887-54-7)
Hazard InformationBack Directory
[Uses]

The monoacidic metabolite of Dacthal, a pre-emergent herbicide.
[Production Methods]

Chlorthal-monomethyl is made by first producing technical-grade chlorthal through the established phthalate-based synthesis in which the tetrachlorinated aromatic core is constructed and then converted to the corresponding acid chloride. The monomethyl ester is formed by reacting this acid chloride with methanol under controlled conditions that limit further esterification, yielding the mono-ester rather than the di-ester. After the reaction, the mixture is neutralised, washed to remove residual reagents, and the crude ester is purified, typically by distillation or crystallisation, to meet technical specifications before being incorporated into herbicide formulations.
[Mechanism of action]

Selective, non-systemic, acts by inhibiting seed germination. Microtubule assembly inhibition.
[Pesticide Type]

Herbicide
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