| Identification | Back Directory | [Name]
(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX | [CAS]
890090-21-8 | [Synonyms]
(Ra,S,S)-7,7′-bis(4′-phenyloxazol-2-yl)-1,1′-spirobiindane
(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX
Oxazole,2,2'-[(1R)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[4,5-dihydro-4-phenyl-,(4S,4'S)- | [Molecular Formula]
C35H30N2O2 | [MDL Number]
MFCD17018766 | [MOL File]
890090-21-8.mol | [Molecular Weight]
510.625 |
| Chemical Properties | Back Directory | [Melting point ]
130-132°C | [alpha ]
+93.0° (c 0.5, CH2Cl2) | [Boiling point ]
712.1±60.0 °C(Predicted) | [density ]
1.29±0.1 g/cm3(Predicted) | [form ]
solid | [pka]
4.12±0.70(Predicted) | [color ]
white | [Sensitive ]
moisture sensitive |
| Questions And Answer | Back Directory | [Reaction]
- Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into N–H bond of anilines.
- Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into O–H bond of phenols.
- Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into O–H bond of water.
- Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into S–H bonds.
- Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into Si–H bonds.
- Chiral ligand used for enantioselective iron-catalyzed intramolecular cyclopropanations.
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