| Identification | Back Directory | [Name]
1,3-Bis(diphenylphosphinomethyl)benzene | [CAS]
89756-88-7 | [Synonyms]
α,α′-Bis(diphenylphosphino)-m-xylene
1,3-Bis(diphenylphosphinomethyl)benzene
[1,3-Phenylenebis(methylene)]bis[diphenyl]phosphine
Phosphine, 1,1'-[1,3-phenylenebis(methylene)]bis[1,1-diphenyl- | [Molecular Formula]
C32H28P2 | [MDL Number]
MFCD16621402 | [MOL File]
89756-88-7.mol | [Molecular Weight]
474.51 |
| Chemical Properties | Back Directory | [Melting point ]
50-55°C | [Boiling point ]
605.0±48.0 °C(Predicted) | [Fp ]
>110℃ | [form ]
powder | [InChI]
1S/C32H28P2/c1-5-16-29(17-6-1)33(30-18-7-2-8-19-30)25-27-14-13-15-28(24-27)26-34(31-20-9-3-10-21-31)32-22-11-4-12-23-32/h1-24H,25-26H2 | [InChIKey]
QLSOZHFOFHARBJ-UHFFFAOYSA-N | [SMILES]
C(P(c1ccccc1)c2ccccc2)c3cccc(CP(c4ccccc4)c5ccccc5)c3 |
| Hazard Information | Back Directory | [Uses]
Reactant for:
- Cyclometalation of pincer ligands
- Insertion of carbon dioxide into (PCP)PDII-Me Bonds
- Synthesis of iridium complexes containing bidentate phosphine ligands
- Transcyclometalation processes
- Synthesis of vinylidene and carbyne complexes
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
|
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|