| Identification | Back Directory | [Name]
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 | [CAS]
909389-99-7 | [Synonyms]
Rh2(S-PTAD)4
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 | [Molecular Formula]
C80H80N4O16Rh2 | [MDL Number]
MFCD09839140 | [MOL File]
909389-99-7.mol | [Molecular Weight]
1559.34 |
| Questions And Answer | Back Directory | [Reaction]
- Enantioselective reactions of carbenoids and olefins.
- Enantioselective C–H insertion reactions of carbenoids.
- Enantioselective oxygen transfer from diazosulfonylamidines.
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| Hazard Information | Back Directory | [Uses]
This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereocontrol. |
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