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909389-99-7

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909389-99-7 Structure

909389-99-7 Structure
IdentificationBack Directory
[Name]

Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
[CAS]

909389-99-7
[Synonyms]

Rh2(S-PTAD)4
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
[Molecular Formula]

C80H80N4O16Rh2
[MDL Number]

MFCD09839140
[MOL File]

909389-99-7.mol
[Molecular Weight]

1559.34
Chemical PropertiesBack Directory
[Melting point ]

>300°C
[alpha ]

+39.1 (c 0.2, CHCl3)
[form ]

Powder
[color ]

green
[InChIKey]

SGEDWOHAUXKUGM-PAPHCAFZSA-J
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H335-H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
[WGK Germany ]

WGK 3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

  1. Enantioselective reactions of carbenoids and olefins.
  2. Enantioselective C–H insertion reactions of carbenoids.
  3. Enantioselective oxygen transfer from diazosulfonylamidines. 
Reactions of 909389-99-7
Hazard InformationBack Directory
[Uses]

This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereocontrol.
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