| Identification | Back Directory | [Name]
Bode Catalyst 1 | [CAS]
919102-70-8 | [Synonyms]
98.0%(LC)
Bode Catalyst 1
Lacβ(1-4)Lac-β-C10>
GUECWMLEUCWYOS-OZYANKIXSA-M
Neu5Acα(2-6)GalβMPGlycoside>
GlcNAcβ(1-2)Manα-1-Ethylazide>
Gal[2346Ac]β(1-3)GlcN3[46Bzd]-β-MP>
3-(4-Nitrophenyl)-5-methyl-2-phenyltetrazolium Chloride >
4-Methoxyphenyl2,6-Bis-O-(4-methylbenzoyl)-β-D-galactopyranoside>
(1R,2R)-1,2-Bis(3,5-dimethylphenyl)-1,2-ethylenediamine Phosphate >
(1S,2S)-1,2-Bis(3,5-dimethylphenyl)-1,2-ethylenediamine Phosphate >
4-Methoxyphenyl3-O-Allyl-2-O-benzyl-4,6-O-benzylidene-β-D-galactopyranoside>
2-Acetamido-3-O-allyl-4,6-O-benzylidene-2-deoxy-beta-D-glucopyranosyl Azide >
4-Methoxyphenyl3-O-Allyl-6-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside>
4-Methoxyphenyl3,4-O-Isopropylidene-6-O-(4-methylbenzoyl)-β-D-galactopyranoside>
4-Methoxyphenyl3-O-Allyl-4,6-O-benzylidene-2-O-(4-methylbenzoyl)-β-D-galactopyranoside>
Succinimidyl6-[[7-(N,N-Dimethylaminosulfonyl)-2,1,3-benzoxadiazol-4-yl]amino]hexanoate>
(-)-(5aS,10bR)-5a,10b-Dihydro-2-mesityl-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride
6-Amino-1,3-naphthalenedisulfonic Acid Monosodium Salt Hydrate[for Determination of 1-Naphthol in 2-Naphthol]>
(-)-(5AS,10br)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium chloride
(-)-(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride
(-)-(5aS,10bR)-5a,10b-Dihydro-2-mesityl-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride
Bode Catalyst 1
[5a-S,10b-R]-2-(2,4,6-Trimethyl-phenyl)-2,5a,6,10b-tetrahydro-4H-5-oxa-2,3-diaza-10c-azonia-cyclopenta[c]fluorene chloride
(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H, 6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate
(-)-(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Monohydrate
(-)-(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxaziniumChlorideMonohydrate>
(-)-(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Monohydrate | [Molecular Formula]
C21H22ClN3OH2O | [MDL Number]
MFCD10566990 | [MOL File]
919102-70-8.mol | [Molecular Weight]
367.88 |
| Chemical Properties | Back Directory | [Melting point ]
212-216 °C | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
powder to crystal | [color ]
White to Light yellow | [optical activity]
[α]20/D -156.0°, c =1 in chloroform |
| Hazard Information | Back Directory | [Uses]
(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H, 6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate can be used as an N-heterocyclic carbene (NHC) organocatalyst:
- In the synthesis of tricyclic β-lactones by reacting 2-bromoenals with 1,3-diketones.
- To functionalize the C2-position of 3-aminobenzofurans using 2-bromoenals as coupling partners.
- In the synthesis of dihydroquinoxalines from substituted bisimines.
- In the preparation of spiro-glutarimide derivatives by reacting cyclic β-ketoamides with α,β-unsaturated aldehydes.
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