ChemicalBook--->CAS DataBase List--->92367-11-8

92367-11-8

92367-11-8 Structure

92367-11-8 Structure
IdentificationBack Directory
[Name]

4-[3-(TrifluoroMethyl)-3H-diazirin-3-yl]benzyl BroMide
[CAS]

92367-11-8
[Synonyms]

4-CF3-diazirine-bromomethyl phenyl
3-[4-(Bromomethyl)phenyl]-3-(trifluoromethyl)diazirine
4-[3-(TrifluoroMethyl)-3H-diazirin-3-yl]benzyl BroMide
3-[4-(Bromomethyl)phenyl]-3-(trifluoromethyl)-3H-diazirine
3-[4-(bromomethyl)phenyl]-3-(trifluoromethyl)-3H-diazirene
3H-Diazirine, 3-[4-(broMoMethyl)phenyl]-3-(trifluoroMethyl)-
4-[3-(Trifluoromethyl)-3H-diazirin-3-yl]benzyl Bromide
[Molecular Formula]

C9H6BrF3N2
[MDL Number]

MFCD19442581
[MOL File]

92367-11-8.mol
[Molecular Weight]

279.057
Chemical PropertiesBack Directory
[Boiling point ]

264.9±50.0 °C(Predicted)
[density ]

1.72±0.1 g/cm3(Predicted)
[refractive index ]

1.5040 to 1.5120
[storage temp. ]

under inert gas (nitrogen or Argon) at 2–8 °C
[form ]

clear liquid
[color ]

Light yellow to Brown
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H290-H314
[Precautionary statements ]

P280-P305+P351+P338-P310
[RIDADR ]

UN 3265 8/PG III
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

2933998090
Hazard InformationBack Directory
[Uses]

3-[4-(Bromomethyl)phenyl]-3-(trifluoromethyl)diazirine is used as a reactant in the synthetic preparation of ginkgolide derivatives incorporating fluorescent and photoactivatable groups for photolabeling studies.
[Synthesis]

4-[3-(Trifluoromethyl)-3H-diazirin-3-yl]benzyl bromide is synthesized by Appel bromination of the alcohol starting material using carbon tetrabromide and triphenylphosphine in dry dichloromethane[1].
[References]

[1]Liu, R. Y., Luo, S.-X. L., Hirst, E. S., Doona, C. J., & Swager, T. M. (2023). Bifunctional diazirine reagent for covalent dyeing of Kevlar and inert polymer materials. Polymer Chemistry, 14(36), 4205–4215. https://doi.org/10.1039/d3py00907f
Spectrum DetailBack Directory
[Spectrum Detail]

4-[3-(TrifluoroMethyl)-3H-diazirin-3-yl]benzyl BroMide(92367-11-8)1HNMR
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