ChemicalBook--->CAS DataBase List--->94124-39-7

94124-39-7

94124-39-7 Structure

94124-39-7 Structure
IdentificationBack Directory
[Name]

TERT-BUTYLMETHOXYPHENYLSILYL BROMIDE
[CAS]

94124-39-7
[Synonyms]

TBMPSIBR
TERT-BUTYLMETHOXYPHENYLBROMOSILANE
BROMO-TERT-BUTYLMETHOXYPHENYLSILANE
TERT-BUTYLMETHOXYPHENYLSILYL BROMIDE
tert-butylmethoxyphenylsilylbromide96+%
tert-Butylmethoxyphenylsilyl Bromide >
tert-Butylmethoxyphenylsilyl Bromide
tert-Butyl(methoxy)phenylbromosilane, TBMPSiBr
Benzene, [bromo(1,1-dimethylethyl)methoxysilyl]-
Bromo-tert-butylmethoxyphenylsilane tert-Butylmethoxyphenylbromosilane
[EINECS(EC#)]

251-228-4
[Molecular Formula]

C11H17BrOSi
[MDL Number]

MFCD00043308
[MOL File]

94124-39-7.mol
[Molecular Weight]

273.24
Chemical PropertiesBack Directory
[Boiling point ]

80-82 °C0.1 mm Hg
[density ]

1.218 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.516
[Fp ]

106 °C
[storage temp. ]

Refrigerator
[form ]

clear liquid to slightly cloudy liquid
[color ]

Colorless to Almost colorless
[Specific Gravity]

1.22
[CAS DataBase Reference]

94124-39-7
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

3
[F ]

10-21
[HS Code ]

2931.90.6000
[HazardClass ]

8
[PackingGroup ]

III
Hazard InformationBack Directory
[Uses]

Tert-Butylmethoxyphenylsilyl Bromide is a reagent for the protection of primary, secondary, and tertiary alcohols; reacts selectively with primary hydroxy groups in dichloromethane; t-butylmethoxyphenylsilyl ethers are highly reactive towards F-, allowing for selective removal in the presence of other silyl protecting groups.
[Precautions]

corrosive, lachrymator; the reagent is light and moisture sensitive and should be handled under an inert atmosphere. Use in a fume hood.
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