| Identification | Back Directory | [Name]
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine | [CAS]
942939-38-0 | [Synonyms]
(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a
3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine
3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine,min.97%
3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97%
3,4-a']dinaphthalen-4-yl)-dibenzo[b,f]azepine >=95% (elemental analysis)
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a,3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97% | [Molecular Formula]
C34H22NO2P | [MDL Number]
MFCD22666424 | [MOL File]
942939-38-0.mol | [Molecular Weight]
507.53 |
| Chemical Properties | Back Directory | [Melting point ]
246 °C | [Boiling point ]
711.5±63.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,2-8°C | [form ]
solid | [pka]
-2.70±0.20(Predicted) | [color ]
yellow | [Optical Rotation]
319.350°(C=1.0039g/100ml CHCL3) | [Sensitive ]
air sensitive, moisture sensitive | [InChI]
1S/C34H22NO2P/c1-5-13-27-23(9-1)19-21-31-33(27)34-28-14-6-2-10-24(28)20-22-32(34)37-38(36-31)35-29-15-7-3-11-25(29)17-18-26-12-4-8-16-30(26)35/h1-22H | [InChIKey]
KOVOHCVLXRKTGN-UHFFFAOYSA-N | [SMILES]
C1(C=CC=C2)=C2C(C3=C(C=CC=C4)C4=CC=C3OP5N6C7=C(C=CC=C7)C=CC8=C6C=CC=C8)=C(O5)C=C1 |
| Questions And Answer | Back Directory | [Reaction]
- The ligand is used in the stereodivergent α-allylation of linear aldehydes with dual iridium and amine catalysis.
- The ligand used in the direct, enantioselective iridium-catalyzed amination and (thio-) etherification of racemic allylic alcohols.
- The ligand used in an asymmetric, rhodium-catalyzed, intramolecular hydroacylation reaction.
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Energy Chemical
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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LaaJoo
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