ChemicalBook--->CAS DataBase List--->95407-69-5

95407-69-5

95407-69-5 Structure

95407-69-5 Structure
IdentificationBack Directory
[Name]

4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL
[CAS]

95407-69-5
[Synonyms]

4-METHOXY-TEMPO
4-Methoxy-TEMPO 97%
4-METHOXY-TEMPO, FREE RADICAL
Methoxytetramethylpiperidineoxyl
4-Methoxy-TEMPO, free radical, 98+%
4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL
4-methoxy-2,2,6,6-tetramethylpiperidinyl-1-oxy
4-Methoxy-2,2,6,6-tetramethyl-1-piperidinyloxy
4-Methoxy-2,2,6,6-tetramethylpiperidine 1-Oxyl 
(2,2,6,6-Tetramethyl-4-methoxypiperidinooxy)radical
[4-Methoxy-2,2,6,6-tetramethylpiperidinooxy]radical
[(2,2,6,6-Tetramethyl-4-methoxypiperidino)oxy]radical
4-methoxy-2,2,6,6-tetramethylpiperidin-1-oxyl radical
4-Methoxy-2,2,6,6-tetramethylpiperidinyloxy,freeradical
4-Methoxy-2,2,6,6-tetramethyl-1-piperidinyloxy, Radical
[(2,2,6,6-Tetramethyl-4-methoxypiperidine-1-yl)oxy]radical
[(4-Methoxy-2,2,6,6-tetramethylpiperidine-1-yl)oxy]radical
4-METHOXY-2,2,6,6-TETRAMETHYL-1-PIPERIDINYLOXY, FREE RADICAL
4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL , FREE RADICAL
4-Methoxy-2,2,6,6-tetramethylpiperidine1-OxylFreeRadical[CatalystforOxidation]>
4-Methoxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical [Catalyst for Oxidation]
4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL FREE RADICAL [CATALYST FOR OXIDATION] 98+%
[EINECS(EC#)]

619-125-2
[Molecular Formula]

C10H20NO2 *
[MDL Number]

MFCD00270334
[MOL File]

95407-69-5.mol
[Molecular Weight]

186.27
Chemical PropertiesBack Directory
[Melting point ]

40.5-44 °C(lit.)
[storage temp. ]

2-8°C
[form ]

powder to crystal
[color ]

Orange to Amber to Dark red
[BRN ]

4740399
[InChI]

1S/C10H20NO2/c1-9(2)6-8(13-5)7-10(3,4)11(9)12/h8H,6-7H2,1-5H3
[InChIKey]

SFXHWRCRQNGVLJ-UHFFFAOYSA-N
[SMILES]

COC1CC(C)(C)N([O])C(C)(C)C1
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[HS Code ]

2933399990
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

4-Methoxy-TEMPO may be employed as catalyst for the synthesis of 2-substituted benzoxazoles, via aerobic oxidation reaction.
[General Description]

4-Methoxy-TEMPO (4-methoxy-2,2,6,6-tetramethyl-1-piperidinyloxy) is an aminoxyl free radical commonly employed for the oxidation reaction of alcohols (primary/secondary). It has been proposed as hindered amine light stabiliser (HALS) model compound. Its reaction with irradiated dilute aqueous suspensions of photocatalytic nanoparticulate titanium dioxide was investigated by electron spin resonance (ESR) and electrospray ionization mass-spectrometry (ESI-MS).
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