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97780-06-8

97780-06-8 Structure

97780-06-8 Structure
IdentificationBack Directory
[Name]

Ethametsulfuron-methyl
[CAS]

97780-06-8
[Synonyms]

MUSTER
DPX-A7881
ETHAMESULFURON
Ethametsulfuron W.P.
ETHAMETSULFURON-METHYL
ETHAMETSULFURON METHYL ESTER
Ethametsulfuron-methyl Standard
Ethametsulfuron suspending agent
Ethametsulfuron Solution, 1000ppm
Ethametsulfuron-methyl@100 μg/mL in Acetonitrile
Ethametsulfuron-methyl@1000 μg/mL in Acetonitrile
Ethametsulfuron-methyl Solution in Acetonitrile, 100μg/mL
methyl2-((4-ethoxy-6-methylamino-1,3,5-triazin-2-yl)carbamoylsulfamoyl)benzo
benzoicacid,2-(((((4-ethoxy-6-(methylamino)-1,3,5-triazin-2-yl)amino)carbonyl
methyl 2-[[4-ethoxy-6-(methylamino)-1,3,5-triazin-2-yl]carbamoylsulfamoyl]benzoate
2-[(4-ethoxy-6-methylamino-1,3,5-triazin-2-yl) carbamoyl sulfamoyl] methyl benzoate
2-[[4-ethoxy-6-(methylamino)-s-triazin-2-yl]carbamoylsulfamoyl]benzoic acid methyl ester
methyl 2-(((((4-ethoxy-6-(methylamino)-1,3,5-triazin-2-yl)amino)carbonyl)amino)sulfonyl)benzoate
2-[[[[[4-Ethoxy-6-methylamino-1,3,5-triazin-2-yl]amino]carbonyl]amino]sulfonyl]benzoic acid methyl ester
2-[[[[[4-ETHOXY-6-(METHYLAMINO)-1,3,5-TRIAZIN-2-YL]AMINO]CARBONYL]AMINO]SULFONYL]BENZOIC ACIDETHYL ESTER
2-[[[[[4-Ethoxy-6-(methylamino)-1,3,5-triazine-2-yl]amino]carbonyl]amino]sulfonyl]benzoic acid methyl ester
Benzoic acid, 2-[[[[[4-ethoxy-6-(methylamino)-1,3,5-triazin-2-yl]amino]carbonyl]amino]sulfonyl]-, methyl ester
[EINECS(EC#)]

619-290-0
[Molecular Formula]

C15H18N6O6S
[MDL Number]

MFCD00486583
[MOL File]

97780-06-8.mol
[Molecular Weight]

410.41
Chemical PropertiesBack Directory
[Melting point ]

192-194°C
[Boiling point ]

316.8℃
[density ]

1.473±0.06 g/cm3(Predicted)
[vapor pressure ]

0-0Pa at 25-45.3℃
[storage temp. ]

0-6°C
[solubility ]

DMSO (Slightly, Sonicated), Methanol (Slightly, Heated, Sonicated)
[form ]

Solid
[pka]

2.54±0.10(Predicted)
[color ]

White to Off-White
[Henry's Law Constant]

2.1×109 mol/(m3Pa) at 25℃, Ebert et al. (2023)
[LogP]

1.590
[EPA Substance Registry System]

Benzoic acid, 2-[[[[[4-ethoxy-6-(methylamino)- 1,3,5-triazin-2-yl]amino] carbonyl]amino]sulfonyl]-, methyl ester(97780-06-8)
Safety DataBack Directory
[Hazard Codes ]

N
[Risk Statements ]

50/53
[Safety Statements ]

60-61
[RIDADR ]

UN3077(solid)
[REACH Registrations]

Active
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Methylamine-->Sodium ethoxide-->Methyl formate-->Metsulfuron methyl-->o-Toluic acid-->Benzenesulfonyl isocyanate-->2-Amino-4-methylamino-6-ethoxy-1,3,5-triazine-->methyl 2-(isocyanatosulphonyl)benzoate
Hazard InformationBack Directory
[Description]

Ethametsulfuron-methyl is a selective herbicide. It is moderately soluble in water, volatile and, based on its chemical properties, presents a high risk of leaching to groundwater. It is relatively persistent in both soil and aqueous systems. It has a low mammalian toxicity but may bio-accumulate. It has a low toxicity to birds and most aquatic species, the exception being aquatic plants including algae. It is moderately toxic to honeybees.
[Uses]

Ethametsulfuron-methyl is a regulator of the early steps of complement activation on mucosal surfaces. It can be used in combination treatment of ohmic heating with various essential oil components for inactivation of food-?borne pathogens in buffered peptone water and salsa.
[Definition]

ChEBI:Ethametsulfuron-methyl is a methyl ester resulting from the formal condensation of the carboxy group of ethametsulfuron with methanol. A herbicide used for the control of broad-leaved weeds in oil seed rape and fodder rape. It has a role as a herbicide and an EC 2.2.1.6 (acetolactate synthase) inhibitor. It is a diamino-1,3,5-triazine, a N-sulfonylurea, an aromatic ether, a benzoate ester and a methyl ester. It is functionally related to an ethametsulfuron.
[Production Methods]

Ethametsulfuron-methyl via a multi-step sulfonylurea synthesis starting from 2-amino-4-methoxy-6-methyl-1,3,5-triazine, which is sulfonylated with 2-(ethoxycarbonyl)ethylsulfonyl chloride in the presence of a base to form the sulfonamide. This intermediate is activated with phosgene or triphosgene to generate the sulfonyl isocyanate, which undergoes condensation with methyl 2-amino-4-methoxy-6-methyl-1,3,5-triazine-5-carboxylate under controlled conditions to construct the urea bridge. Final hydrolysis, methyl esterification, and recrystallization yield ethametsulfuron-methyl.
[Agricultural Uses]

Ethametsulfuron-methyl is used as Herbicide,Plant growth inhibitor. Pending in EU countries. Registered for use in the U.S.
[Trade name]

A-7881®; DPX-A 7881® (application withdrawn); MUSTER®
[Mechanism of action]

Selective. Inhibits plant amino acid synthesis - acetohydroxyacid synthase AHAS
[Pesticide Type]

Herbicide
97780-06-8 suppliers list
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