| Identification | Back Directory | [Name]
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE | [CAS]
99438-28-5 | [Synonyms]
(+)-B-methoxydiisocamphenylborane
(+)-B-methoxydiisocamphenylborane
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE
(+)-B-Methoxydiisopinocampheylborane
(-)-DIISOPINOCAMPHEYLMETHOXYBORANE HYDRATE
(+)-B-methoxydiisopinocampheylborane hydrate
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE HYDRATE
(-)-beta-Methoxydiisopinocampheylboranehydrate
cis-1,2,3,4-Tetrahydro-2-phenyl-1-naphthaleneaceticaci
(+)-B-Methoxydiisopinocampheylborane,(+)-Diisopinocampheylmethoxyborane
Methoxybis((1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane
Borinic acid, B,B-bis[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-, methyl ester | [Molecular Formula]
C21H37BO | [MDL Number]
MFCD21332906 | [MOL File]
99438-28-5.mol | [Molecular Weight]
316.33 |
| Chemical Properties | Back Directory | [Boiling point ]
365.6±9.0 °C(Predicted) | [density ]
0.95±0.1 g/cm3(Predicted) | [Fp ]
>230 °F | [storage temp. ]
2-8°C | [form ]
solid | [Appearance]
Colorless to light yellow Solid | [BRN ]
6370228 | [InChI]
InChI=1S/C21H37BO/c1-12-15-8-13(19(15,2)3)9-16(12)21(6)17-10-14(20(17,4)5)11-18(21)22-23-7/h12-18,22H,8-11H2,1-7H3/t12-,13+,14-,15+,16+,17+,18+,21-/m1/s1 | [InChIKey]
BRIUCEGTDHQYCH-VSDAKGBHSA-N | [SMILES]
B([C@H]1C[C@@]2([H])C[C@@]([H])(C2(C)C)[C@]1([C@H]1C[C@]2([H])C[C@]([H])(C2(C)C)[C@H]1C)C)OC |
| Hazard Information | Back Directory | [Uses]
(-)-B-Methoxydiisopinocampheylborane hydrate is an intermediate used in the synthesis of homoallylic alcohol''s and several complex natural products. | [Uses]
(+)?-?B-?Methoxydiisopinocamp?heylborane is a chiral catalyst used in synthetic organic chemistry such as the bacterial macrolide glycoside (-?)?-?Lyngbyaloside B which maintains antiproliferative activity. | [Uses]
Reactant involved in:
- Oxidative cyclization and alkylation for synthesis of ionomycin
- Intramolecular conjugate addition for tetrahydropyran synthesis
- Aldol addition and Suzuki coupling reactions
- Allylation
- Synthesis of alkanols
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