1341134-01-7
中文名称
MOF:MIL-88B(FE)
英文名称
MIL-88B(Fe)
CAS
1341134-01-7
分子式
C24H12Fe3O13
分子量
675.88
MOL 文件
1341134-01-7.mol
1341134-01-7 结构式
基本信息
中文别名
MIL-88B(FE)金属有机骨架TRIS [Μ-[1,4-苯二甲酸(2-)-ΚO1:ΚO'1]]-Μ3-氧三铁
英文别名
MOF:MIL-88B(FE)Tris[μ-[1,4-benzenedicarboxylato(2-)-κO1:κO'1]]-μ3-oxotriiron
所属类别
材料化学：发光材料常见问题列表
结构特性
| 配位金属 | Fe |
| 配体 | 对苯二甲酸（CAS：100-21-0） |
| 孔径 | 未活化含有溶剂状态下1.1-1.5nm;活化后<1nm |
| 粒径 | 300-600nm |
| 比表面 | N2测BET基本无吸附 |
稳定性
MIL-88B(Fe)在空气中稳定，在水溶液和酸性条件下较稳定；高热稳定性、热分解温度大于400℃应用领域
储气材料和吸附材料;具有特殊的“呼吸”效应参考文献
文献 1
[1] Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks. https://doi.org/10.1126/science.1137975
[2] Design and synthesis of biopolymer-derived porous graphitic carbon covered iron-organic frameworks for depollution of arsenic from waters. https://doi.org/10.1016/j.chemosphere.2020.126769
[3] Enhanced Fenton-like catalysis by iron-based metal organic frameworks for degradation of organic pollutants. https://doi.org/10.1016/j.jcat.2017.09.015
[4] Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways. https://doi.org/10.1021/cs501169t
[5] How Linker's Modification Controls Swelling Properties of Highly Flexible Iron(III) Dicarboxylates MIL-88. https://doi.org/10.1021/ja206936e